A convenient and useful method of preparation of α-bromo enones from the corresponding enones using organic ammonium tribromide (OATB)

被引：33

作者：

Bose, G ^{[1
]}

Barua, PMB ^{[1
]}

Chaudhuri, MK ^{[1
]}

Kalita, D ^{[1
]}

Khan, AT ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Guwahati 781039, Assam, India

来源：

CHEMISTRY LETTERS | 2001年 / 04期

关键词：

D O I：

10.1246/cl.2001.290

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Various acyclic a-bromo enones 2 as well as cyclic alpha -bromo enones 4 can be prepared from the corresponding acyclic enones 1 and cyclic enones 3 respectively, in a one-pot procedure by employing organic ammonium tribromide, such as cetyltrimethylammonium tribromide (CetTMATB) or tetrabutylammonium tribromide (TBATB) in presence of K2CO3 in dichloromethane at 0 degreesC to room temperature under very mild conditions in good yields(2).

引用

页码：290 / 291

页数：2

共 15 条

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