A New Copper Coordination Polymer with Magnetic Property Based on 3-(1,2,4-Triazol-1-yl)benzoic Acid

被引：0

作者：

Zhang Heng-Da ^{[1
,2
]}

Wang Shuai-Hua ^{[1
]}

Wu Shao-Fan ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Fujian, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100039, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2017年 / 36卷 / 11期

基金：

中国国家自然科学基金;

关键词：

copper coordination polymer; hydrothermal reaction; crystal structure; magnetic property; ORGANIC FRAMEWORKS; LIGANDS; COMPLEXES; DESIGN;

D O I：

10.14102/j.cnki.0254-5861.2011-1615

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A copper coordination polymer, namely [CuL2(H2O)(2)]center dot H2O 1 (HL = 3-(1,2,4-triazol-1-yl) benzoic acid) has been synthesized by the hydrothermal reaction under 140 degrees C. The structure of 1 was characterized by single-crystal X-ray diffraction analysis, elemental analyses, powder X-ray diffraction, IR spectroscopy, and thermogravimetric analysis. Single-crystal X-ray diffraction analysis reveals that 1 crystallizes in P2(1)/n space group with a = 12.374(5), b = 12.730(5), c = 12.561(5) angstrom, beta = 91.105(9)degrees, V = 1978.2(14) angstrom(3), Z = 4, Dc = 1.618 g/cm(3), mu = 1.160 mm(-1), F(000) = 964, the final R = 0.0449 and wR = 0.1443 with I > 2 sigma(I). Magnetic measurements show that 1 exhibits antiferromagnetic interactions by the analysis of magnetic test data.

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页码：1912 / 1917

页数：6

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