Kinetic of hydrate formation of propane and its mixture with methane in a circulating flow reactor

被引：15

作者：

Sarshar, M. ^{[2
,4
]}

Fathikalajahi, J. ^{[1
,3
]}

Esmaeilzadeh, F. ^{[3
]}

机构：

[1] Sultan Qaboos Univ, Petr & Chem Engn Dept, Muscat, Oman

[2] Inst Engn, Fars Engn Res Ctr, Shiraz, Iran

[3] Shiraz Univ, Dept Chem & Petr Engn, Sch Engn, Shiraz, Iran

[4] Shiraz Univ Technol, Sch Chem Engn, Shiraz, Iran

来源：

FLUID PHASE EQUILIBRIA | 2010年 / 298卷 / 01期

关键词：

Kinetics; Gas hydrate; Circulating flow reactor; Modeling; Simulation; DISSOLVED WATER; LOOP; NUCLEATION; DEPOSITION; CO2;

D O I：

10.1016/j.fluid.2010.06.016

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Kinetics of hydrate formation for propane and its mixture with 73% methane have been studied experimentally and theoretically at pressure up to 2 MPa and temperature up to 277.65 K in a 10 m circulating flow reactor. A mathematical model has been developed for the process of hydrate formation based on crystallization, mass transfer and thermodynamics concepts. The amounts of gas consumptions due to hydrate formation are measured experimentally and predicted by the model. The agreement between the experimental measured gas consumptions and predicted values by the mathematical model are very good and the average deviation errors in the prediction of gas consumption are less than 10%. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：38 / 47

页数：10

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