A high-performance and stable Cu/Beta for adsorption-catalytic oxidation in-situ destruction of low concentration toluene

被引：29
|
作者：
Du, Yueying [1 ]
Xiao, Gaofei [1 ]
Guo, Ziyang [1 ]
Lin, Beilong [1 ]
Fu, Mingli [1 ,2 ,3 ]
Ye, Daiqi [1 ,2 ,3 ]
Hu, Yun [1 ,2 ,3 ]
机构：
[1] South China Univ Technol, Sch Environm & Energy, Guangzhou 510006, Peoples R China
[2] Guangdong Prov Key Lab Atmospher Environm & Pollut, Guangzhou 510006, Peoples R China
[3] Minist Educ, Key Lab Pollut Control & Ecosyst Restorat Ind Clus, Guangzhou 510006, Peoples R China
来源：
SCIENCE OF THE TOTAL ENVIRONMENT | 2022年 / 833卷
关键词：
Cu; Beta; Toluene; Adsorption-catalytic oxidation integration; VOLATILE ORGANIC-COMPOUNDS; ACTIVATED CARBON; ZEOLITE; OXIDES; CHLOROBENZENE; REMOVAL;
D O I：
10.1016/j.scitotenv.2022.155288
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
Finding a cost-effective treatment to remove of low concentrations of volatile organic compounds (VOCs) is still a challenge. In this study, a Cu/Beta material was developed for in situ adsorption-catalytic oxidation of low concentrations of toluene. The results showed that the addition of Cu enhanced the adsorption and catalytic oxidation of toluene by Beta zeolite. Cu7/Beta with a Cu+ ratio of close to 50% performed best. The high adsorption of Cu7/Beta was mainly attributed to the abundant Cu+ species and the micro-mesoporous structure of the Beta zeolite, and the high catalytic oxidation was attributed to the lattice oxygen in the uniformly dispersed CuO. Finally, the adsorption intermediates and reaction pathways in the catalytic oxidation of toluene were clarified using XPS and DRIFTS spectra. This work provides new strategies for the development of efficient and stable adsorption-catalytic oxidation in situ destruction materials.
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页数：12
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