β-Fluorinated porpholactones and metal complexes: synthesis, characterization and some spectroscopic studies

被引：18

作者：

Hu, Ji-Yun ^{[1
]}

Wu, Zhuo-Yan ^{[1
]}

Chai, Ke ^{[2
]}

Yang, Zi-Shu ^{[1
]}

Meng, Yin-Shan ^{[1
]}

Ning, Yingying ^{[1
]}

Zhang, Jing ^{[2
]}

Zhang, Jun-Long ^{[1
]}

机构：

[1] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China

[2] Univ Chinese Acad Sci, Coll Mat Sci & Optoelectron Technol, Beijing 100049, Peoples R China

来源：

INORGANIC CHEMISTRY FRONTIERS | 2017年 / 4卷 / 09期

关键词：

PHOTOPHYSICAL PROPERTIES; ELECTRONIC-STRUCTURE; 1ST SYNTHESIS; C-H; PORPHYRIN; OXIDATION; DEFLUORINATION; LACTONIZATION; SUBSTITUENTS; DERIVATIVES;

D O I：

10.1039/c7qi00375g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We describe the synthesis of beta-fluorinated porpholactones by oxidation of the fluorinated C=C bond of the pyrrolic subunit in porphyrin using the "RuCl3 + Oxone (R)" protocol. The electron-withdrawing effects of beta-fluorine on the absorption, fluorescence, phosphorescence and redox properties of the beta-fluoroporpholactones were studied. A potential application of the beta-fluoroporpholactones was demonstrated in sensitizing near-IR (NIR) emissive ytterbium, giving a high quantum yield (58%) and long luminescence time (525 mu s) in CD2Cl2.

引用

页码：1539 / 1545

页数：7

共 50 条

[31] BODIPY Dyes Bearing Multibranched Fluorinated Chains: Synthesis, Structural, and Spectroscopic Studies
Espinoza, Maria I. Martinez
Sori, Lorenzo
Pizzi, Andrea
Terraneo, Giancarlo
Moggio, Ivana
Arias, Eduardo
Pozzi, Gianluca
Orlandi, Simonetta
Dichiarante, Valentina
Metrangolo, Pierangelo
Cavazzini, Marco
Bombelli, Francesca Baldelli
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2019, 25 (38) : 9078 - 9087
[32] Spectroscopic, potentiometric and thermodynamic studies of azo rhodanines and their metal complexes
El-Sonbati, A. Z.
El-Bindary, A. A.
Abd El-Meksoud, S. A.
Belal, A. A. M.
El-Boz, R. A.
[J]. JOURNAL OF MOLECULAR LIQUIDS, 2014, 199 : 538 - 544
[33] Polymer complexes. LXXVII. Synthesis, characterization, spectroscopic studies and immune response in cattle of quinoline polymer complexes
El-Sonbati, A. Z.
Diab, M. A.
Mohamed, G. G.
Saad, M. A.
Morgan, Sh. M.
El-Sawy, S. E. A.
[J]. APPLIED ORGANOMETALLIC CHEMISTRY, 2019, 33 (08)
[34] Synthesis, characterization, catalytic and antimicrobial studies of ruthenium(III) complexes
Thilagavathi, Natarajan
Jayabalakrishnan, Chinnasamy
[J]. CENTRAL EUROPEAN JOURNAL OF CHEMISTRY, 2010, 8 (04): : 842 - 851
[35] Transition Metal Complexes of Isonicotinoylhydrazone-4-diphenylaminobenzaldehyde: Synthesis, Characterization and Antimicrobial Studies
Mitu, L.
Ilis, M.
Raman, N.
Imran, M.
Ravichandran, S.
[J]. E-JOURNAL OF CHEMISTRY, 2012, 9 (01) : 365 - 372
[36] Synthesis, spectral characterization and biological studies of quinoline based ligands and their transition metal complexes
Narayanachar
Dhumwad, Shreedhar D.
Suresh, D. K.
[J]. MAIN GROUP CHEMISTRY, 2012, 11 (02) : 135 - 149
[37] Cobalt(III) Complexes of Some Antimalarial Drugs: Synthesis, Characterization, and in vitro Antiprotozoal Studies
Ajibade, Peter A.
Kolawole, Gabriel A.
[J]. SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2010, 40 (04) : 273 - 278
[38] Synthesis and characterization of alkali metal iminophosphoranomethanide complexes
Stevens, Matthew P.
Liu, Yu
Cooke, Kale
Hawker, Rebecca R.
Ortu, Fabrizio
[J]. POLYHEDRON, 2024, 261
[39] Fluorinated benzimidazolium salts: Synthesis, characterization, molecular docking studies and inhibitory properties against some metabolic enzymes
Zengin, Ramazan
Gok, Yetkin
Demir, Yeliz
Sen, Betul
Taskin-Tok, Tugba
Aktas, Aydin
Demirci, Ozlem
Gulcin, Ilhami
Aygun, Muhittin
[J]. JOURNAL OF FLUORINE CHEMISTRY, 2023, 267
[40] Fluorine-19 NMR spectroscopic studies of phenyl-fluorinated iron tetraarylporphyrin complexes
Song, B
Yu, BS
[J]. BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2003, 24 (07) : 981 - 985

← 1 2 3 4 5 →