Europium(II) and ytterbium(II) aryloxide chemistry:: synthesis and crystal structure of [Eu(OC6H3Bu2t-2,6)2(THF)3]•0.75C7H8 and [Yb(OC6H3Bu2t-2,6)2(NCMe)4]

被引：12

作者：

Carretas, J ^{[1
]}

Branco, J ^{[1
]}

Marçalo, J ^{[1
]}

Domingos, K ^{[1
]}

de Matos, AP ^{[1
]}

机构：

[1] Inst Tecnol & Nucl, Dept Quim, P-2686953 Sacavem, Portugal

来源：

POLYHEDRON | 2003年 / 22卷 / 11期

关键词：

europium; ytterbium; MVS; dissolution in ammonia; aryloxides;

D O I：

10.1016/S0277-5387(03)00193-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of europium and ytterbium with 2,6-di-tert-butylphenol were studied by the metal vapour synthesis technique and by dissolution in liquid ammonia. The lanthanide complexes [Eu(OC6H3Bu2'-2,6)(2)(THF)(3)].0.75C(7)H(8) I and [Yb(OC6H3Bu2'-2,6)(2)(NCMe)(4)] 2 were synthesized and characterized by X-ray diffraction studies. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：1425 / 1429

页数：5

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