1H-Imidazole-4-carbonitrile

被引：1

作者：

Less, GB ^{[1
]}

Rasmussen, PG ^{[1
]}

Kampf, JW ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷

关键词：

D O I：

10.1107/S1600536805014509

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, C4H3N3, was synthesized in three steps from diaminomaleonitrile in an overall yield of 38%. Single-crystal X-ray analysis reveals that the compound crystallizes exclusively as the 1H-imidazole-4-carbonitrile isomer. This heterocycle forms a non-centrosymmetric crystal structure and packs with an appreciable dipole moment, making it a good candidate for non-linear optical applications.

引用

页码：O1704 / O1706

页数：3

共 21 条

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[2]

BRUKER, 2001, SMART VERSION 5 054

[3]

CATALAN J, 1983, HETEROCYCLES, V20, P1717

[4] Probing hydrogen bonding and proton mobility in dicyanoimidazole monomers and polymers [J].