Spatial and temporal hydrochemistry variations of karst water in Gunung Sewu, Java']Java, Indonesia

A hydrogeochemical study was conducted in the Gunung Sewu Karst, Java Island, Indonesia. The main objective of this study is to describe the spatial and temporal variations of hydrochemistry that occur in the central and western parts of Gunung Sewu. Discharge measurements for a one-year period are taken in some karst springs or underground rivers to define their discharge hydrograph. Furthermore, baseflow separation analysis was conducted to determine the base flow percentage throughout the year. Water sampling for hydrogeochemical analysis was taken every month to represent the dry and rainy season conditions. To describe the hydrogeochemical processes, a scatter plot analysis with a small sample size was conducted. The results showed that the hydrochemistry of karst water in the study area has different characteristics spatially and temporally. Within the dry season, the dominant hydrogeochemical process is water-rock interaction (precipitation of calcite mineral), indicated by achieving the maximum level of Ca2+, HCO3-, electrical conductivity, base flow percentage, and SI calcite, with the lowest level of log PCO2 in the water. In addition, the dry season hydrochemistry is characterized by a strong relationship between electrical conductivity-calcium/bicarbonate, base flow percentage-discharge, base flow percentage-SI calcite, and SI calcite-log PCO2. Spatially, the different level of correlations between these parameters depended on the sampling location, flow recharge, and the conduit development. Conversely, in the rainy season, the hydrogeochemical process shifted from water-rock interaction to dilution of rainwater as a result of rain water supply through a conduit system channel, which is characterized by declining Ca2+, HCO3-, electrical conductivity, base flow percentage, and SI calcite, with the highest level of log PCO2 in the water. The dilution of rainwater process also caused a decline in the correlation of some hydro-geochemical parameters.