Bronsted Acid Catalyzed Peterson Olefinations

被引：16

作者：

Britten, Thomas K. ^{[1
]}

McLaughlin, Mark G. ^{[1
]}

机构：

[1] Manchester Metropolitan Univ, Dept Nat Sci, Chester St, Manchester M1 5GD, Lancs, England

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2020年 / 85卷 / 02期

基金：

英国医学研究理事会;

关键词：

NUCLEOPHILIC-SUBSTITUTION; REAGENTS; KETONES;

D O I：

10.1021/acs.joc.9b02489

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A mild and facile Peterson olefination has been developed employing low catalyst loading of the Bronsted acid HNTf2. The reactions are typically performed at room temperature, with the reaction tolerant to a range of useful functionalities. Furthermore, we have extended this methodology to the synthesis of enynes.

引用

页码：301 / 305

页数：5

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