Adsorption of SO2 on Ni(100) and Ni(111) surfaces

被引：9
|
作者：
Yokoyama, T
Terada, S
Imanishi, A
Kitajima, Y
Kosugi, N
Ohta, T
机构：
[1] NATL LAB HIGH ENERGY PHYS,PHOTON FACTORY,TSUKUBA,IBARAKI 305,JAPAN
[2] INST MOL SCI,OKAZAKI,AICHI 444,JAPAN
来源：
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA | 1996年 / 80卷
关键词：
D O I：
10.1016/0368-2048(96)02946-5
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
Surface structures and electronic properties of submonolayer sulfur dioxide SO2 molecularly adsorbed on Ni(111) and Ni(100) have been investigated by means of S K-edge SEXAFS, S and O K-edge NEXAFS, S 1s and 2p XPS, UPS, and ab initio SCF-MO calculation. S K-edge NEXAFS and SEXAFS have clarified that on both surfaces the SO2 molecule adsorbs with the molecular plane parallel to the surface and with the bridge site occupation of the S atom. The SCF-MO calculation has verified such a flat-lying structure. Charge transfer from the Ni 3d band to the SO2 pi* orbital has also been elucidated by S and O K-edge NEXAFS, S 1s and 2p XPS, UPS and the SCF-MO calculation.
引用
收藏
页码：161 / 164
页数：4
相关论文
共 50 条
  • [41] Methane dissociation and adsorption on Ni(111), Pt(111), Ni(100), Pt(100), and Pt(110)-(1x2): Energetic study
    Nave, Sven
    Tiwari, Ashwani Kumar
    Jackson, Bret
    JOURNAL OF CHEMICAL PHYSICS, 2010, 132 (05):
  • [42] INVERSE PHOTOEMISSION SPECTROSCOPY OF H, CO AND NO ADSORBED AT NI(100) AND NI(111) SURFACES
    REIMER, W
    FINK, T
    KUPPERS, J
    SURFACE SCIENCE, 1988, 193 (1-2) : 259 - 270
  • [43] SURFACE RAMAN-SPECTROSCOPY OF PYRIDINE ADSORBED ON NI(111) AND NI(100) SURFACES
    HARRADINE, D
    CAMPION, A
    JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1986, 4 (03): : 1467 - 1468
  • [44] Water adsorption on clean Ni(111) and p(2x2)-Ni(111)-O surfaces calculated from first principles
    Wippermann, S.
    Schmidt, W. G.
    PHYSICAL REVIEW B, 2008, 78 (23):
  • [45] SO2 adsorption on thin Pd/Ni(111) films studied by X-ray absorption fine structure spectroscopy
    Terada, S
    Yokoyama, T
    Okamoto, Y
    Kiguchi, M
    Kitajima, Y
    Ohta, T
    SURFACE SCIENCE, 1999, 442 (02) : 141 - 148
  • [46] DFT study of 2-butyne-1,4-diol adsorption on Ni(111) or Ni(100) clusters
    Sakamoto, Takeshi
    Tachikawa, Hiroto
    Azumi, Kazuhisa
    APPLIED SURFACE SCIENCE, 2012, 258 (18) : 6785 - 6792
  • [47] LOW-TEMPERATURE ADSORPTION OF CO AND O-2 ON NI(100) AND NI(111) - EVIDENCE FOR PRECURSORS
    SHAYEGAN, M
    GLOVER, RE
    PARK, RL
    JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1986, 4 (03): : 1333 - 1335
  • [48] RESONANCE-LIKE PHENOMENA IN ACTIVATED DISSOCIATIVE ADSORPTION - N-2+ ON NI(100) AND NI(111)
    AKAZAWA, H
    MURATA, Y
    JOURNAL OF CHEMICAL PHYSICS, 1988, 88 (05): : 3317 - 3321
  • [49] INTERACTION OF HE ATOMS WITH (111) AND (100) SURFACES OF CU AND NI
    LENARCICPOLJANEC, K
    HODOSCEK, M
    LOVRIC, D
    GUMHALTER, B
    SURFACE SCIENCE, 1991, 251 : 706 - 711
  • [50] ADSORPTION OF CO ON CLEAN AND OXYGEN COVERED NI(111) SURFACES
    CONRAD, H
    ERTL, G
    KUPPERS, J
    LATTA, EE
    SURFACE SCIENCE, 1976, 57 (02) : 475 - 484
12345