Synthesis and Photovoltaic Properties of Conjugated Copolymers with Benzo[1,2-b:4,5-b′]dithiophene and Bis(thiophene)phthalimide Units

被引：25
|
作者：
Zhang, Guobing [1 ]
Fu, Yingying [2 ]
Zhang, Qing [1 ]
Xie, Zhiyuan [2 ]
机构：
[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Dept Polymer Sci & Engn, Shanghai 200240, Peoples R China
[2] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
来源：
MACROMOLECULAR CHEMISTRY AND PHYSICS | 2010年 / 211卷 / 24期
关键词：
bis(thiophene)phthalimide; conjugated polymers; open-circuit voltage; photovoltaics; POLYMER SOLAR-CELLS; PERFORMANCE; THIOPHENE; BANDGAP;
D O I：
10.1002/macp.201000430
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Two new donor/acceptor copolymers PBDTPhBT1 and PBDTPhBT2 with alternating benzodithiophene (BDT) and bisthiophene-phthalimide (PhBT) units were synthesized by Stille coupling reaction. The copolymers showed identical optical bandgaps of 1.98 eV. The HOMO energy levels are -5.35 and -5.32 eV for PBDTPhBT1 and PBDTPhBT2, respectively. The bulk heterojunction solar cell devices based on these copolymers as donors and PC71BM as acceptor displayed high open-circuit voltages of 0.90-0.93 V and achieved power conversion efficiency of 1.54% under the illumination of AM 1.5, 100 mW.cm-2
引用
收藏
页码：2596 / 2601
页数：6
相关论文
共 50 条
  • [1] Synthesis and photovoltaic properties of alternative copolymers of benzo[1,2-b:4,5-b′]dithiophene and thiophene
    Min, Jie
    Peng, Bo
    He, Youjun
    Zhang, Maojie
    Zhang, Zhi-Guo
    Zhang, Jing
    Guo, Xia
    Cui, Chaohua
    Deng, Dan
    Li, Yongfang
    POLYMER BULLETIN, 2012, 68 (08) : 2107 - 2119
  • [2] Synthesis and photovoltaic properties of alternative copolymers of benzo[1,2-b:4,5-b′]dithiophene and thiophene
    Jie Min
    Bo Peng
    Youjun He
    Maojie Zhang
    Zhi-Guo Zhang
    Jing Zhang
    Xia Guo
    Chaohua Cui
    Dan Deng
    Yongfang Li
    Polymer Bulletin, 2012, 68 : 2107 - 2119
  • [3] Synthesis and Photovoltaic Properties of Copolymers Based on Benzo[1,2-b:4,5-b′]dithiophene and Thiophene with Different Conjugated Side Groups
    Gu, Zhaojie
    Tang, Peng
    Zhao, Bin
    Luo, Hao
    Guo, Xia
    Chen, Huajie
    Yu, Gui
    Liu, Xinping
    Shen, Ping
    Tan, Songting
    MACROMOLECULES, 2012, 45 (05) : 2359 - 2366
  • [4] Synthesis and Photovoltaic Properties of New Conjugated Polymers Based on Benzo[1,2-b:4,5-b′]Dithiophene
    Lim, Eunhee
    Lee, Sungkoo
    Lee, Kyeong K.
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2012, 12 (05) : 4243 - 4247
  • [5] Synthesis and photovoltaic properties of copolymers based on benzo[1,2-b:4,5-b′]dithiophene and thiazole with different conjugated side groups
    Liu, Xunshan
    Huang, Yuanshuai
    Cao, Zhencai
    Weng, Chao
    Chen, Huajie
    Tan, Songting
    POLYMER CHEMISTRY, 2013, 4 (17) : 4737 - 4745
  • [6] Synthesis and Photovoltaic Properties of a Copolymer of Benzo[1,2-b:4,5-b′]dithiophene and Bithiazole
    Zhang, Maojie
    Fan, Haijun
    Guo, Xia
    He, Youjun
    Zhang, Zhi-Guo
    Min, Jie
    Zhang, Jing
    Zhao, Guangjin
    Zhan, Xiaowei
    Li, Yongfang
    MACROMOLECULES, 2010, 43 (21) : 8714 - 8717
  • [7] Synthesis and Photovoltaic Properties of Copolymers Based on Benzo[1,2-b:4,5-b′]dithiophene and Thiophene with Electron-Withdrawing Side Chains
    Nie, Yujuan
    Zhao, Bin
    Tang, Peng
    Jiang, Peng
    Tian, Zongfang
    Shen, Ping
    Tan, Songting
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2011, 49 (16) : 3604 - 3614
  • [8] Synthesis and photovoltaic properties of thieno[3,2-b]thiophenyl substituted benzo[1,2-b:4,5-b′]dithiophene copolymers
    Xiao, Zeyun
    Subbiah, Jegadesan
    Sun, Kuan
    Jones, David J.
    Holmes, Andrew B.
    Wong, Wallace W. H.
    POLYMER CHEMISTRY, 2014, 5 (23) : 6710 - 6717
  • [9] Synthesis and photovoltaic properties of conjugated copolymers with benzo[1,2-b:4,5-b′]dithiophene and thiadiazolo[3,4-c] pyridine moieties
    Kang, Huaiyin
    Zhao, Bin
    Cao, Zhencai
    Zhong, Jun
    Li, Haohao
    Pei, Yong
    Shen, Ping
    Tan, Songting
    EUROPEAN POLYMER JOURNAL, 2013, 49 (09) : 2738 - 2747
  • [10] Synthesis and photovoltaic properties of alkylthiothienyl-substituted benzo[1,2-b:4,5-b′]dithiophene D-A copolymers with different accepting units
    Zhang, Xiwen
    Chen, Lixia
    Wang, Guo
    Zhang, Zhi-Guo
    Li, Yongfang
    Shen, Ping
    SYNTHETIC METALS, 2016, 211 : 121 - 131
12345