Optical properties and molecular orientation of self-assembled monolayer using surface plasmon resonance spectroscopy

被引：11
作者：
Kim, SH [1 ]
Ock, KS
Kim, JH
Koh, KN
Kang, SW
机构：
[1] Kyungpook Natl Univ, Coll Engn, Dept Dyeing & Finishing, Taegu 702701, South Korea
[2] Kyungpook Natl Univ, Grad Sch, Dept Sensor Engn, Taegu 702701, South Korea
[3] Kyungpook Natl Univ, Sensor Technol Res Ctr, Dept Sensor Engn, Taegu 702701, South Korea
[4] Ajou Univ, Dept Mol Sci & Technol, Suwon 442749, South Korea
来源：
DYES AND PIGMENTS | 2001年 / 48卷 / 01期
关键词：
self-assembled monolayer (SAM); spiroxazine dye; photochromism; surface plasmon resonance (SPR); tilt angle; molecular orientation;
D O I：
10.1016/S0143-7208(00)00090-5
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
We report evidence of photoisomerization-induced changes in thin films of spiroxazine-alkanethiol self-assembled monolayers (SAM) by surface plasmon resonance (SPR). Geometry optimization by MO calculations reveals that the tilt angle of spiroxazine moiety is around 30 degrees. (C) 2001 Published by Elsevier Science Ltd.
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页码：1 / 6
页数：6
相关论文
共 22 条
  • [1] QUARTZ-CRYSTAL MICROBALANCE AND SURFACE-PLASMON RESONANCE STUDY OF SURFACTANT ADSORPTION ONTO GOLD AND CHROMIUM-OXIDE SURFACES
    CARUSO, F
    SERIZAWA, T
    FURLONG, DN
    OKAHATA, Y
    [J]. LANGMUIR, 1995, 11 (05) : 1546 - 1552
  • [2] Durr H., 1990, PHOTOCHROMISM MOL SY
  • [3] INFRARED SPECTRA OF MONOLAYERS ON METAL MIRRORS
    FRANCIS, SA
    ELLISON, AH
    [J]. JOURNAL OF THE OPTICAL SOCIETY OF AMERICA, 1959, 49 (02) : 131 - 138
  • [4] GORDON JG, 1977, OPT COMMUN, V22, P374, DOI 10.1016/S0030-4018(97)90032-8
  • [5] DESIGN OF A REFLECTION-ABSORPTION EXPERIMENT FOR STUDYING IR-SPECTRUM OF MOLECULES ADSORBED ON A METAL-SURFACE
    GREENLER, RG
    [J]. JOURNAL OF VACUUM SCIENCE & TECHNOLOGY, 1975, 12 (06): : 1410 - 1417
  • [6] Heavens O. S., 1991, OPTICAL PROPERTIES T
  • [7] JORGENSON RC, 1993, SPIE P BIOM OPT C CA
  • [8] POLAR ORIENTATION OF DYES IN ROBUST MULTILAYERS BY ZIRCONIUM PHOSPHATE-PHOSPHONATE INTERLAYERS
    KATZ, HE
    SCHELLER, G
    PUTVINSKI, TM
    SCHILLING, ML
    WILSON, WL
    CHIDSEY, CED
    [J]. SCIENCE, 1991, 254 (5037) : 1485 - 1487
  • [9] A NEW PHOTOCHROMIC SPIRO[3H-1,4-OXAZINE]
    KAWAUCHI, S
    YOSHIDA, H
    YAMASHINA, N
    OHIRA, M
    SAEDA, S
    IRIE, M
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1990, 63 (01) : 267 - 268
  • [10] The preparation and spectroscopic study of self-assembled monolayers of a UV-sensitive spiroxazine dye on gold
    Kim, SH
    Lee, SM
    Park, JH
    Kim, JH
    Koh, KN
    Kang, SW
    [J]. DYES AND PIGMENTS, 2000, 45 (01) : 51 - 57
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