Heterogeneous Catalysis

被引：553

作者：

Schloegl, Robert ^{[1
,2
]}

机构：

[1] Max Planck Gesell, Fritz Haber Inst, D-14195 Berlin, Germany

[2] Max Planck Inst Chem Energy Convers, D-45470 Mulheim, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 11期

关键词：

heterogeneous catalysis; reaction kinetics; surface chemistry; X-RAY-ABSORPTION; N-BUTANE OXIDATION; DENSITY-FUNCTIONAL-THEORY; PALLADIUM HYDROGENATION CATALYSTS; PROPANE-SELECTIVE OXIDATION; LOCAL REACTION-KINETICS; SOLID-STATE CHEMISTRY; METAL-SURFACE-AREA; TEMPERATURE-PROGRAMMED DESORPTION; SPATIOTEMPORAL SELF-ORGANIZATION;

D O I：

10.1002/anie.201410738

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A heterogeneous catalyst is a functional material that continually creates active sites with its reactants under reaction conditions. These sites change the rates of chemical reactions of the reactants localized on them without changing the thermodynamic equilibrium between the materials.

引用

页码：3465 / 3520

页数：56

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