Toward Well-Defined Metal-Polymer Interfaces: Temperature-Controlled Suppression of Subsurface Diffusion and Reaction at the Calcium/Poly(3-Hexylthiophene) Interface

被引：27

作者：

Bebensee, Fabian ^{[1
,2
]}

Schmid, Martin ^{[1
,2
]}

Steinrueck, Hans-Peter ^{[1
,2
]}

Campbell, Charles T. ^{[3
]}

Gottfried, J. Michael ^{[1
,2
]}

机构：

[1] Univ Erlangen Nurnberg, Lehrstuhl Phys Chem 2, D-91058 Erlangen, Germany

[2] ICMM, D-91058 Erlangen, Germany

[3] Univ Washington, Dept Chem, Seattle, WA 98195 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 35期

关键词：

POLYIMIDE; GROWTH;

D O I：

10.1021/ja104029r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The thickness of the reaction zone at the interface between calcium and regioregular poly(3-hexylthiophene), which is one of the best performing metal/polymer combinations in photovoltaic devices, depends critically on the temperature of the polymer during the initial phase of metal deposition. It is shown that deposition at 130 K reduces the thickness of the reaction zone, an effect that also persists after warming to room temperature.

引用

页码：12163 / 12165

页数：3

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