Two chiral coordination polymers constructed from (1R,2R)-1,2-diaminocyclohexane derivative: Syntheses, structures and properties

被引：9

作者：

Xue, Zhenzhen ^{[1
,2
]}

Zhang, Hao ^{[1
,2
]}

Sheng, Tianlu ^{[1
]}

Wen, Yuehong ^{[1
]}

Wang, Yong ^{[1
,2
]}

Hu, Shengmin ^{[1
]}

Li, Haoran ^{[1
,2
]}

Zhuo, Chao ^{[1
,2
]}

Wu, Xintao ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2015年 / 55卷

基金：

中国国家自然科学基金;

关键词：

Chiral coordination polymers; Coordination modes; Second harmonic generation; Photoluminescence; METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; SHG RESPONSE; PHOTOLUMINESCENT PROPERTIES; POSITIONAL ISOMERISM; LIGANDS; LUMINESCENCE; COMPONENTS; COMPLEXES; RESOLUTION;

D O I：

10.1016/j.inoche.2015.03.024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two chiral coordination polymers were synthesized by using a chiral ligand (1R,2R)-1,2-bis(4-(1,2,4-triazolyl)) cydohexane to assemble with Zn(II)/Ag(I) salts. The different coordination modes of the ligand result in two diverse structures, such as a OD structure for 1 and a 1D chain for 2, respectively. The chiral nature of compounds 1 and 2 was confirmed by circular dichroism spectra (CD) and second harmonic generation (SHG) efficiency measurements. Furthermore, the photoluminescent properties of compounds 1 and 2 have been investigated in the solid state at ambient temperature. (C) 2015 Published by Elsevier B.V.

引用

页码：99 / 102

页数：4

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