Two chiral coordination polymers constructed from (1R,2R)-1,2-diaminocyclohexane derivative: Syntheses, structures and properties

被引：9
作者：
Xue, Zhenzhen [1 ,2 ]
Zhang, Hao [1 ,2 ]
Sheng, Tianlu [1 ]
Wen, Yuehong [1 ]
Wang, Yong [1 ,2 ]
Hu, Shengmin [1 ]
Li, Haoran [1 ,2 ]
Zhuo, Chao [1 ,2 ]
Wu, Xintao [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2015年 / 55卷
基金：
中国国家自然科学基金;
关键词：
Chiral coordination polymers; Coordination modes; Second harmonic generation; Photoluminescence; METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; SHG RESPONSE; PHOTOLUMINESCENT PROPERTIES; POSITIONAL ISOMERISM; LIGANDS; LUMINESCENCE; COMPONENTS; COMPLEXES; RESOLUTION;
D O I：
10.1016/j.inoche.2015.03.024
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two chiral coordination polymers were synthesized by using a chiral ligand (1R,2R)-1,2-bis(4-(1,2,4-triazolyl)) cydohexane to assemble with Zn(II)/Ag(I) salts. The different coordination modes of the ligand result in two diverse structures, such as a OD structure for 1 and a 1D chain for 2, respectively. The chiral nature of compounds 1 and 2 was confirmed by circular dichroism spectra (CD) and second harmonic generation (SHG) efficiency measurements. Furthermore, the photoluminescent properties of compounds 1 and 2 have been investigated in the solid state at ambient temperature. (C) 2015 Published by Elsevier B.V.
引用
收藏
页码：99 / 102
页数：4
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