Electropolymerized of Aniline as A New Molecularly Imprinted Polymer for Determination of Phenol A Study for Phenol Sensor

被引:0
作者
Rahmadhani, Sri [1 ]
Setiyanto, Henry [1 ]
Zulfikar, Muhammad Ali [1 ]
机构
[1] Inst Teknol Bandung, Analyt Chem Res Grp, Bandung, Indonesia
来源
2017 INTERNATIONAL SEMINAR ON SENSORS, INSTRUMENTATION, MEASUREMENT AND METROLOGY (ISSIMM) | 2017年
关键词
electrochemical sensor; molecularly imprinted polymer; carbon paste electrode; polyaniline; phenol; VOLTAMMETRY; SURFACE;
D O I
暂无
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
This paper deals with the application of polyaniline conducting polymer as a new sensor material for detection of phenol. The sensor is designed using bare carbon paste electrode (CPE), nonimprinted polymer-modified electrode (CPE/NIP) and imprinted polymer-modified electrode (CPE/MIP). These electrodes were prepared by electropolymerization of the monomer (aniline) in the presence of phenol as the template onto a carbon paste electrode. A CPE/MIP sensor which is modified with carbon paste electrode was able to detect the analyte more selectively. Several results regarding a decreasing in sensor activity were discussed. The ability of the electrodes to recognize the analyte was characterized using cyclic voltammetry (CV) in of 0.1M K-3[Fe(CN)(6)]/0.1M K-4[Fe(CN)(6)] acted as an electroactive specie at scan rate100 mV/s between potentials of -0.2 - 0.8 V by cyclic voltammetry under the optimal experimental condition.
引用
收藏
页码:124 / 128
页数:5
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