Studies on switching mechanisms in Pd-nanodot embedded Nb2O5 memristors using scanning tunneling microscopy

被引:25
作者
Hota, M. K. [1 ]
Bera, M. K. [1 ]
Verma, S. [2 ]
Maiti, C. K. [1 ]
机构
[1] Indian Inst Technol, Dept Elect & Elect Commun Engn, VLSI Engn Lab, Kharagpur 721302, W Bengal, India
[2] Inst Phys, Bhubaneswar 751005, Orissa, India
关键词
Memristor; STM; Nb2O5; MEMORY;
D O I
10.1016/j.tsf.2012.07.026
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Current imaging tunneling spectrum obtained from scanning tunneling microscopy has been used to probe the formation and/or rupture of conductive filaments responsible for bipolar switching in Pd nano-dots embedded Nb2O5 memristors. Filamentary conduction mechanism has been confirmed by scanning tunneling microscopy study using a Pt-Ir tip that enabled performing electroforming and reset operations at the nanoscale. The back and forth transition between the fully oxidized and metallic sub-oxide states of niobium under applied bias, as observed from X-ray photoelectron spectroscopy, is believed to be the source of bipolar switching in Nb2O5 memristors. The incorporation of Pd nanodots in Nb2O5 matrix plays a critical role by acting as an oxygen ion reservoir and/or by polarizing a large volume of oxygen vacancies. The formation and/or rupture of the conducting filaments through trapping-detrapping phenomena are found to boost the memristive switching performance. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:6648 / 6652
页数:5
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