Remote substituents controlling catalytic polymerization by very active and robust neutral nickel(II) complexes

被引：171
作者：
Zuideveld, MA
Wehrmann, P
Röhr, C
Mecking, S
机构：
[1] Univ Freiburg, Inst Makromol Chem, D-79104 Freiburg, Germany
[2] Univ Freiburg, Freiburger Mat Forschungszentrum, D-79104 Freiburg, Germany
[3] Univ Freiburg, Inst Anorgan Chem, D-79104 Freiburg, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 07期
关键词：
alkenes; homogeneous catalysis; polymerization; polymers; substituent effects;
D O I：
10.1002/anie.200352062
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Remote control: Substituents strongly affect the catalytic properties of complexes 1 in ethylene polymerization, despite their remoteness from the active center. An appropriate substitution pattern provides very active and robust catalysts.
引用
收藏
页码：869 / 873
页数：5
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