A bioinspired self assembled dimeric porphyrin pocket that binds electron accepting ligands

被引:11
作者
Borjesson, Karl [1 ]
Woller, Jakob G. [1 ]
Parsa, Elham [1 ]
Martensson, Jerker [1 ]
Albinsson, Bo [1 ]
机构
[1] Chalmers, Dept Chem & Biol Engn, S-41296 Gothenburg, Sweden
基金
瑞典研究理事会;
关键词
DNA ORIGAMI; CIRCULAR-DICHROISM; THERMAL-STABILITY; ENERGY-TRANSFER; DUPLEX; SCAFFOLD; ZINC; NANOSTRUCTURES; DERIVATIVES; BEHAVIOR;
D O I
10.1039/c2cc17434k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A binding pocket consisting of two zinc porphyrins self assembled by Watson-Crick base pairing is presented. The porphyrin binding pocket is located in the confined environment of a lipid membrane whereas the DNA is located in the water phase. Bidentate electron accepting ligands are shown to coordinate in-between the two porphyrins.
引用
收藏
页码:1793 / 1795
页数:3
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