Electropolymerization and characterization of 3,4-ethylenedioxy thiophene on glassy carbon electrode and study of ions transport of the polymer during redox process

被引：4

作者：

Moradi, Atefeh ^{[1
]}

Emamgolizadeh, Abbas ^{[1
]}

Omrani, Abdollah ^{[1
]}

Rostami, Abbas Ali ^{[1
]}

机构：

[1] Univ Mazandaran, Fac Chem, Babol Sar, Iran

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 2012年 / 125卷 / 03期

关键词：

poly (3; 4-ethylenedioxythiophene); electropolymerization; morphology; Butler-Volmer equation; CONDUCTING POLYMERS; POLY(3,4-ETHYLENEDIOXYTHIOPHENE); OXIDATION;

D O I：

10.1002/app.36508

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(3,4-ethylenedioxythiophene) (PEDOTh) films were deposited on glassy carbon (GC) electrodes from organic electrolytes containing the monomer in a solution of acetonitrile (AN). The effect of the supporting electrolyte used during electropolymerization, on the redox behavior, surface morphology, and degree of crystallinity of the films has been investigated by FTIR, cyclic voltammetry, and scanning electron microscopy (SEM) techniques. The use of LiPF6 leads to a higher electropolymerization efficiency and an increase of electroactivity and crystallinity of the polymer. On the basis of voltammetric studies of the Nernst and ButlerVolmer equations, we concluded that BF4-, ClO4-, and PF6- anions are the mobile species during the redox process of the PEDOTh films. (c) 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012

引用

页码：2407 / 2416

页数：10

共 4 条

[1] Synthesis and characterization of β-substituted 3,4-ethylenedioxy terthiophene monomers for conducting polymer applications
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SYNTHETIC METALS, 2013, 171 : 23 - 31
[2] Selective Determination of Serotonin on Poly(3,4-ethylenedioxy pyrrole)-single-walled Carbon Nanotube-Modified Glassy Carbon Electrodes
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[3] Electrochemical study of niclosamide at poly(3,4-ethylenedioxythiophene) modified glassy carbon electrode
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[4] Electropolymerization of a poly(3,4-ethylenedioxythiophene) and functionalized, multi-walled, carbon nanotubes counter electrode for dye-sensitized solar cells and characterization of its performance
Zhang, Jun
Li, Xiaoxue
Guo, Wei
Hreid, Tubshin
Hou, Jinfeng
Su, Haiquan
Yuan, Zhuobin
ELECTROCHIMICA ACTA, 2011, 56 (09) : 3147 - 3152

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