A modular and efficient synthesis of functional titanocenes

被引:56
|
作者
Gansäuer, A
Franke, D
Lauterbach, T
Nieger, M
机构
[1] Univ Bonn, Kekule Inst Organ Chem & Biochem, D-53121 Bonn, Germany
[2] Univ Bonn, Inst Anorgan Chem, D-53121 Bonn, Germany
关键词
D O I
10.1021/ja054185r
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A modular synthesis of functional titanocenes featuring building blocks is described. The approach allows straightforward access to large numbers of structurally diverse titanocenes that are pertinent for catalysis, structural studies, and bioinorganic chemistry. Among the functional groups introduced are amino acids, sugars, and fluorescence labels that are attached to the cyclopentadienyl ligand as esters and amides. Copyright © 2005 American Chemical Society.
引用
收藏
页码:11622 / 11623
页数:2
相关论文
共 50 条
  • [21] Synthesis of sila-bridged titanocenes and desilylation reaction
    Wang, BQ
    Xu, SS
    Zhou, XZ
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 1999, 20 (01): : 50 - 53
  • [22] The synthesis and cytotoxic evaluation of a series of benzodioxole substituted titanocenes
    Sweeney, Nigel J.
    Claffey, James
    Muller-Bunz, Helge
    Pampillon, Clara
    Strohfeldt, Katja
    Tacke, Matthias
    APPLIED ORGANOMETALLIC CHEMISTRY, 2007, 21 (02) : 57 - 65
  • [23] SYNTHESIS OF ANSA-TITANOCENES VIA DOUBLE SKATTEBOL REARRANGEMENT
    NANTZ, MH
    SUTTON, SC
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 205 : 41 - INOR
  • [24] Synthesis and cytotoxicity studies of steroid-functionalized titanocenes as potential anticancer drugs: sex steroids as potential vectors for titanocenes
    Li Ming Gao
    José L. Vera
    Jaime Matta
    Enrique Meléndez
    JBIC Journal of Biological Inorganic Chemistry, 2010, 15 : 851 - 859
  • [25] Modular synthesis of efficient schedules in a timed discrete event plant
    Boel, RK
    Montoya, FJ
    PROCEEDINGS OF THE 39TH IEEE CONFERENCE ON DECISION AND CONTROL, VOLS 1-5, 2000, : 16 - 21
  • [26] An Efficient, Modular Approach for the Synthesis of (+)-Strictifolione and a Related Natural Product
    Jayasinghe, Susanthi
    Venukadasula, Phanindra K. M.
    Hanson, Paul R.
    ORGANIC LETTERS, 2014, 16 (01) : 122 - 125
  • [27] Synthesis and cytotoxicity studies of steroid-functionalized titanocenes as potential anticancer drugs: sex steroids as potential vectors for titanocenes
    Gao, Li Ming
    Vera, Jose L.
    Matta, Jaime
    Melendez, Enrique
    JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY, 2010, 15 (06): : 851 - 859
  • [28] An efficient modular synthesis of conjugated ω-(p-hexyloxyphenyl)polyenals
    Domagalska, BW
    Syper, L
    Wilk, KA
    SYNTHESIS-STUTTGART, 2001, (16): : 2463 - 2469
  • [29] 2-Azidoacrylamides as compact platforms for efficient modular synthesis
    Takemura, Hinano
    Goto, Sayuri
    Hosoya, Takamitsu
    Yoshida, Suguru
    CHEMICAL COMMUNICATIONS, 2020, 56 (99) : 15541 - 15544
  • [30] Modular Synthesis of Biodegradable Diblock Copolymers for Designing Functional Polymersomes
    Katz, Joshua S.
    Zhong, Sheng
    Ricart, Brendon G.
    Pochan, Darrin J.
    Hammer, Daniel A.
    Burdick, Jason A.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (11) : 3654 - +