Practical Synthesis of β-Acyl and β-Alkoxycarbonyl Heterocyclic Sulfones

被引：46

作者：

Pospisil, Jiri ^{[1
]}

Sato, Hitoshi ^{[1
]}

机构：

[1] Catholic Univ Louvain, Inst Condensed Matter & Nanosci Mol Solids & Reac, B-1348 Louvain, Belgium

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 76卷 / 07期

关键词：

MICHAEL ADDITION; ALPHA; BETA-UNSATURATED KETONES; ASYMMETRIC ORGANOCATALYSIS; STEREOSELECTIVE-SYNTHESIS; CONJUGATE ADDITION; CHEMISTRY; ALDEHYDES; ALKENYL; ESTERS; ACIDS;

D O I：

10.1021/jo102326p

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A short and efficient synthesis for beta-acyl and beta-alkoxycarbonyl heterocyclic sulfones containing benzothiazol (BT) and phenyltetrazol (PT) heterocydic core is presented here. The method seems to be general and provides the desired C-nudeophiles in very good to excellent yields from readily available starting materials.

引用

页码：2269 / 2272

页数：4

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