Synthesis of Diisothiocyanato-Functionalized 2,2′-Bipyridines

被引：8
|
作者：
Kremer, Christopher [1 ]
Luetzen, Arne [1 ]
机构：
[1] Univ Bonn, Kekule Inst Organ Chem & Biochem, D-53121 Bonn, Germany
来源：
SYNTHESIS-STUTTGART | 2011年 / 02期
关键词：
bipyridine; isothiocyanates; amines; thiophosgene; cross-coupling reactions; COMPLEXES; RECOGNITION; BIPYRIDINE; THIOUREA; LIGANDS;
D O I：
10.1055/s-0030-1258342
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Three new diisothiocyanato-functionalized 2,2'-bipyridines have been synthesized in four consecutive steps. Starting from 4-amino-2-chloro- and 2-amino-6-bromopyridine, respectively, we first prepared the corresponding diamino-2,2'-bipyridines via homo-or Negishi cross-coupling reactions which were subsequently reacted with thiophosgene.
引用
收藏
页码：210 / 212
页数：3
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