Oxidative addition of methyl iodide and CO migratory insertion in a cationic rhodium complex of a S,N,S tridentate ligand

被引：24

作者：

Bassetti, M

Capone, A

Mastrofrancesco, L

Salamone, M

机构：

[1] Univ Roma La Sapienza, CNR, Ist Metodol Chim, I-00185 Rome, Italy

[2] Univ Roma La Sapienza, Dipartimento Chim, I-00185 Rome, Italy

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 12期

关键词：

D O I：

10.1021/om030199z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cationic rhodium(I) carbonyl complex mer-[Rh(L)(CO)]PF6 coordinated by a tridentate S,N,S donor ligand (L = 2,6-bis(benzylthiomethyl)pyridine) reacts with MeI to give the corresponding acetyl derivative [Rh(L)(COMe)I]PF6, by consecutive oxidative addition-migratory insertion reactions via observable methyl-rhodium(III) intermediate complexes. Rate constants and activation parameters have been obtained for both reaction steps in MeCN, and compared with those of complexes coordinated by mono- and bidentate ligands. This is the first report on the organometallic reactivity of a rhodium(I) and carbonyl complex of S,N,S ligands.

引用

页码：2535 / 2538

页数：4

共 37 条

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2-6

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