Synthesis, structure and luminescence study of two cadmium(II) coordination polymers with hetero donor ligands: Expansion of network dimensionality from 2D to 3D through hydrogen bonding

被引：5
作者：
Dalai, Sudipta [1 ]
Chowdhuri, Durga Sankar [1 ]
Bera, Madhusudan [1 ]
Rana, Abhinandan [1 ]
Guidolin, Nicol [2 ]
Zangrando, Ennio [2 ]
机构：
[1] Vidyasagar Univ, Dept Chem & Chem Technol, Midnapore 721102, W Bengal, India
[2] Univ Trieste, Dipartimento Sci Chim, I-34127 Trieste, Italy
来源：
INORGANICA CHIMICA ACTA | 2010年 / 363卷 / 14期
关键词：
Coordination polymer; 3-Pyridinepropionic acid; 2-Pyrazinecarboxylic acid; 5-Aminotetrazole; pi-pi Interactions; Luminescence; FRAMEWORKS; DESIGN; CHEMISTRY; ZINC; NETS;
D O I：
10.1016/j.ica.2010.05.021
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two coordination polymers of cadmium with formula [Cd(pyp)(2)(H2O)(2)](n) (1) and {[Cd-2(pyzca)(3)(atr) (H2O)]center dot H2O}(n) (2) [pypH = 3-pyridinepropionic acid, pyzcaH = 2-pyrazinecarboxylic acid and atrH = 5-aminotetrazole] have been synthesized and structurally characterized by X-ray single crystal diffraction analysis. Both complexes display 2D structures that extend into a 3D network by means of hydrogen bonding. The crystal packing of both complexes is reinforced by pi-pi interactions between adjacent aromatic rings. The fluorescence study indicates intraligand pi-pi* charge transfer, which is the reason for emission in both the complexes. (c) 2010 Elsevier B. V. All rights reserved.
引用
收藏
页码：3700 / 3705
页数：6
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