Circularly Polarized Luminescence of Curium: A New Characterization of the 5f Actinide Complexes

被引：47

作者：

Law, Ga-Lai ^{[1
]}

Andolina, Christopher M. ^{[1
]}

Xu, Jide ^{[1
]}

Luu, Vinh ^{[3
]}

Rutkowski, Philip X. ^{[2
]}

Muller, Gilles ^{[3
]}

Shuh, David K. ^{[2
]}

Gibson, John K. ^{[2
]}

Raymond, Kenneth N. ^{[1
,2
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Chem Sci, Berkeley, CA 94720 USA

[3] San Jose State Univ, Dept Chem, San Jose, CA 95192 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 37期

基金：

美国国家卫生研究院;

关键词：

INTRAMOLECULAR ENERGY-TRANSFER; AROMATIC LIGANDS; LANTHANIDE; AMERICIUM(III); CM(III); IONS; PHOTOLUMINESCENCE; ENANTIOPURE; CRYSTALS; EUROPIUM;

D O I：

10.1021/ja306354n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A key distinction between the lanthanide (4f) and the actinide (5f) transition elements is the increased role of f-orbital covalent bonding in the latter. Circularly polarized luminescence (CPL) is an uncommon but powerful spectroscopy which probes the electronic structure of chiral, luminescent complexes or molecules. While there are many examples of CPL spectra for the lanthanides, this report is the first for an actinide. Two chiral, octadentate chelating ligands based on orthoamide phenol (IAM) were used to complex curium(III). While the radioactivity kept the amount of material limited to micromole amounts, spectra of the highly luminescent complexes showed significant emission peak shifts between the different complexes, consistent with ligand field effects previously observed in luminescence spectra.

引用

页码：15545 / 15549

页数：5

共 36 条

[31] Circularly Polarized Luminescence in Enantiopure Europium and Terbium Complexes with Modular, All-Oxygen Donor Ligands [J].

Seitz, Michael ;

Do, King ;

Ingram, Andrew J. ;

Moore, Evan G. ;

Muller, Gilles ;

Raymond, Kenneth N. .

INORGANIC CHEMISTRY, 2009, 48 (17) :8469-8479

[32] Assessing a solids-biased density-gradient functional for actinide metals [J].

Soederlind, Per ;

Gonis, A. .

PHYSICAL REVIEW B, 2010, 82 (03)

[33] Electronic spectroscopy of UO22+, NUO+ and NUN: an evaluation of time-dependent density functional theory for actinides [J].

Tecmer, Pawel ;

Gomes, Andre Severo Pereira ;

Ekstroem, Ulf ;

Visscher, Lucas .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (13) :6249-6259

[34] Spectroscopic Properties and Hydration of the Cm(III) Aqua Ion from 10 to 85 °C [J].

Tian, Guoxin ;

Edelstein, Norman M. ;

Rao, Linfeng .

JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 115 (10) :1933-1938

[35] Octadentate Cages of Tb(III) 2-Hydroxyisophthalamides: A New Standard for Luminescent Lanthanide Labels [J].

Xu, Jide ;

Corneillie, Todd M. ;

Moore, Evan G. ;

Law, Ga-Lai ;

Butlin, Nathaniel G. ;

Raymond, Kenneth N. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (49) :19900-19910

[36] PHOTOLUMINESCENCE OF AMERICIUM(III) IN AQUEOUS AND ORGANIC SOLUTIONS [J].

YUSOV, AB .

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY-ARTICLES, 1990, 143 (02) :287-294

← 1 2 3 4 →