Properties of nanocrystalline cubic silicon carbide thin films prepared by hot-wire chemical vapor deposition using SiH4/CH4/H2 at various substrate temperatures

被引:15
作者
Tabata, Akirnori [1 ]
Komura, Yusuke [1 ]
Hoshide, Yoshiki [1 ]
Narita, Tomoki [2 ]
Kondo, Akihiro [2 ]
机构
[1] Nagoya Univ, Dept Elect Engn & Comp Sci, Nagoya, Aichi 4648603, Japan
[2] Gifu Univ, Dept Elect & Elect Engn, Gifu 5011193, Japan
关键词
hot-wire CVD; silicon carbide; 3C-SiC; nanocrystalline; low-temperature deposition;
D O I
10.1143/JJAP.47.561
中图分类号
O59 [应用物理学];
学科分类号
摘要
Silicon carbide (SiC) thin films were prepared by hot-wire chemical vapor deposition from SiH4/CH4/H-2 gases, and the influence of substrate temperature, T-s (104 < T-s < 434 degrees C), on the properties of the SiC thin films was investigated. X-ray diffraction patterns and Raman scattering spectra revealed that nanocrystalline cubic SiC (nc-3C-SiC) films grew at T-s above 187 degrees C, while completely amorphous films grew at T-s = 104 degrees C. Fourier transform infrared absorption spectra revealed that the crystallinity of the nc-3C-SiC was improved with increasing T, up to 282 degrees C and remained almost unchanged with a further increase in T,, from 282 to 434 degrees C. The spin density was reduced monotonically with increasing T-s.
引用
收藏
页码:561 / 565
页数:5
相关论文
共 27 条
[1]   Structural and optical properties of hydrogenated amorphous silicon-carbon alloys grown by plasma-enhanced chemical vapour deposition at various rf powers [J].
Ambrosone, G. ;
Coscia, U. ;
Ferrero, S. ;
Giorgis, F. ;
Mandracci, P. ;
Pirri, C.F. .
Philosophical Magazine B: Physics of Condensed Matter; Statistical Mechanics, Electronic, Optical and Magnetic Properties, 2002, 82 (01) :35-46
[2]   Fabrication of microcrystalline cubic silicon carbide/crystalline silicon heterojunction solar cell by hot wire chemical vapor deposition [J].
Banerjee, Chandan ;
Narayanan, Karman Lakshmi ;
Haga, Keisuke ;
Sritharathikhun, Jaran ;
Miyajima, Shinsuke ;
Yamada, Akira ;
Konagai, Makoto .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2007, 46 (01) :1-6
[3]   HYDROGEN EVOLUTION AND DEFECT CREATION IN AMORPHOUS SI-H ALLOYS [J].
BIEGELSEN, DK ;
STREET, RA ;
TSAI, CC ;
KNIGHTS, JC .
PHYSICAL REVIEW B, 1979, 20 (12) :4839-4846
[4]   Amorphous and microcrystalline silicon deposited by low-power electron-cyclotron resonance plasma-enhanced chemical-vapor deposition [J].
Conde, JP ;
Schotten, V ;
Arekat, S ;
Brogueira, P ;
Sousa, R ;
Chu, V .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1997, 36 (1A) :38-49
[5]   Effect of filament and substrate temperatures on the structural and electrical properties of SiC thin films grown by the HWCVD technique [J].
Dasgupta, A. ;
Huang, Y. ;
Houben, L. ;
Klein, S. ;
Finger, F. ;
Carius, R. ;
Luysberg, M. .
THIN SOLID FILMS, 2008, 516 (05) :622-625
[6]   Defect structure of carbon rich a-SiC:H films and the influence of gas and heat treatments [J].
Friessnegg, T ;
Boudreau, M ;
Mascher, P ;
Knights, A ;
Simpson, PJ ;
Puff, W .
JOURNAL OF APPLIED PHYSICS, 1998, 84 (02) :786-795
[7]   Atomically flat 3C-SiC epilayers by low pressure chemical vapor deposition [J].
Ishida, Y ;
Takahashi, T ;
Okumura, H ;
Yoshida, S ;
Sekigawa, T .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 1997, 36 (11) :6633-6637
[8]   Structural properties of microcrystalline SiC deposited at low substrate temperatures by HWCVD [J].
Klein, S. ;
Houben, L. ;
Carius, R. ;
Finger, F. ;
Fischer, W. .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2006, 352 (9-20) :1376-1379
[9]   Low substrate temperature deposition of crystalline SiC using HWCVD [J].
Klein, S ;
Carius, R ;
Finger, F ;
Houben, L .
THIN SOLID FILMS, 2006, 501 (1-2) :169-172
[10]   Electronic properties of low temperature microcrystalline silicon carbide prepared by Hot Wire CVD [J].
Klein, Stefan ;
Dasgupta, Arup ;
Finger, Friedhelm ;
Carius, Reinhard ;
Bronger, Torsten .
THIN SOLID FILMS, 2008, 516 (05) :630-632