(2E)-3-(3,5-Dichloro-4-methoxy-2,6-di-methylphenyl)1-(2,4-dichlorophenyl)-prop-2-en-1-one

被引:0
作者
Jasinski, Jerry P.
Butcher, Ray J.
Mayekar, Anil N.
Narayana, B.
Yathirajan, H. S.
机构
[1] Keene State Coll, Dept Chem, Keene, NH 03435 USA
[2] Howard Univ, Dept Chem, Washington, DC 20059 USA
[3] Univ Mysore, Dept Studies Chem, Mysore 570006, Karnataka, India
[4] Mangalore Univ, Dept Studies Chem, Mangalagangothri 574199, India
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷
关键词
single-crystal X-ray study; T=296 K; mean alpha(C-C)=0.011 angstrom; R factor=0.081; wR factor=0.239; data-to-parameter ratio=18.7;
D O I
10.1107/S1600536807047654
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title molecule, C18H14Cl4O2, the angle between the mean planes of the 3,5-dichloro-4-methoxy-2,6-dimethyl-phenyl and 2,4-dichlorophenyl groups is 47.6 (2)degrees. The 4-methoxy group, with a torsion angle of 91.9 (9)degrees, is twisted away from the plane of the 3,5-dichloro-2,6-dimethylphenyl ring in an anticlinal conformation. The ketone O atom of the prop-2-en-1-one group is twisted in a synclinal conformation with the 2,4-dichlorophenyl group [ torsion angle = 45.5 (11)degrees]. The crystal packing is stabilized by intermolecular C-H center dot center dot center dot O hydrogen bonding between the ketone O atom from the prop-2-en-1-one group and an H atom from a nearby 2,4-dichlorophenyl group, which link the molecules into chains along the a axis. The 3,5-dichloro-4-methoxy-2,6-dimethylphenyl and 2,4-dichlorophenyl groups are aligned obliquely parallel to the ac face, with the benzene rings stacked obliquely along the b axis for both groups.
引用
收藏
页码:O4229 / U2575
页数:14
相关论文
共 50 条
  • [1] (2E)-1-(2,4-Dichlorophenyl)-3-(2,3,4trimethoxyphenyl)prop-2-en-1-one
    Butcher, Ray J.
    Jasinski, Jerry P.
    Mayekar, Anil N.
    Narayana, B.
    Yathirajan, H. S.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O4059 - U3147
  • [2] 2E)-3-(2-Bromo-5-methoxyphenyl)-1(2,4-dichlorophenyl) prop-2-en-1-one
    Butcher, Ray J.
    Jasinski, Jerry P.
    Yathirajan, H. S.
    Narayana, B.
    Mayekar, Anil N.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O4253 - U2781
  • [3] (2E)-1-(2,4-Dichlorophenyl)-3-[3-(4-nitrophenyl)-1-phenyl-1-H-pyrazol-4-yl]-prop-2-en-1-one
    Isloor, Arun M.
    Malladi, Shridhar
    Gerber, Thomas
    van Brecht, Benjamin
    Betz, Richard
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O616 - U1505
  • [4] (2E)-1-(2,4-Dichlorophenyl)-3-[4-(di-ethylamino)2-hydroxyphenyl] prop2-en-1-one
    Jasinski, Jerry P.
    Butcher, Ray J.
    Mayekar, Anil N.
    Narayana, B.
    Yathirajan, H. S.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O4231 - U2588
  • [5] (2E)-3-[4-(Benzyloxy)phenyl]-1-(2,6-dichloro-3-fluorophenyl)prop-2-en-1-one
    Praveen, Aletti S.
    Yathirajan, Hemmige S.
    Gerber, Thomas
    van Brecht, Benjamin
    Betz, Richard
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O3386 - +
  • [6] (2E)-3-(4-Methylphenyl)-1-(pyridin-3-yl)-prop-2-en-1-one
    Oliveiria, Mauricio de Sousa
    de Souza, Wanderson Costa
    Napolitano, Hamilton B.
    Oliver, Allen G.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : 02585 - +
  • [7] (2E)-1-(3,5-Dihydroxyphenyl)-3-(4-methoxyphenyl)prop-2-en-1-one
    Ezhilarasi, K. S.
    Jonathan, D. Reuben
    Sathya, Shanmugam
    Prathebha, K.
    Usha, G.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : O608 - +
  • [8] (2E)-3-(Dimethylamino)-1-(4-fluoro-phenyl)prop-2-en-1-one
    Kant, Rajni
    Gupta, Vivek K.
    Kapoor, Kamini
    Deshmukh, Madhukar B.
    Patil, D. R.
    Anbhule, P. V.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O3110 - +
  • [9] (E)-3-(4-Methylphenyl)-1-(1,3-thiazol-2-yl)prop-2-en-1-one
    Palaniappan, Annamalai
    Arulmozhivarman, Arumugam
    Ramachandran, Rajamanickam
    Srinivasan, Subramanian
    Senthan, Sivakolunthu
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O1875 - +
  • [10] (E)-3-(2,4-Dimethoxyphenyl)-1-(3,4,5-trimethoxyphenyl)prop-2-en-1-one
    Wu, Jianzhang
    Qiu, Junyan
    Wu, Xiaokai
    Yang, Shulin
    Liu, Yonggen
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68 : o154