Synthesis and Crystal Structures of Two Novel Complexes with N-[2-(5-Bromo-2-Hydroxybenzylideneamino)Ethyl]-4-Methylbenzenesulfonamide as Ligand

被引：3

作者：

Li, Shu-Ni ^{[1
]}

Zhai, Quan-Guo ^{[1
]}

Hu, Man-Cheng ^{[1
]}

Jiang, Yu-Cheng ^{[1
]}

机构：

[1] Shaanxi Normal Univ, Key Lab Macromol Sci Shaanxi Prov, Sch Chem & Mat Sci, Xian 710062, Shaanxi, Peoples R China

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2011年 / 41卷 / 01期

关键词：

N-Tosylethylenediamine; Sulfonamide Schiff base; Crystal structure; Supramolecular architecture; METAL-SALEN COMPLEXES; SCHIFF-BASE LIGANDS; ELECTROCHEMICAL SYNTHESIS; DIIMINE;

D O I：

10.1007/s10870-010-9825-4

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Two novel complexes constructed from the sulfonamide Schiff base ligand H (2) L, N-[2-(5-bromo-2-hydroxybenzylideneamino)ethyl]-4-methylbenzene-sulfonamide, [Cu(HL)(2)] (1) and [CuL(H(2)O)] (2) are synthesized and characterized via X-ray single-crystal diffraction, elemental analysis, FT-IR and UV-Vis. 1 and 2 both form 1-D supramolecular architectures by pi-pi stacking interactions. 1 and 2 both crystallize in monoclinic, with space group C2/c and P2/c for 1 and 2, with unit cell parameters a = 27.640(18) , b = 7.907(5) , c = 17.945(14) , beta = 118.27(2)A degrees, V = 3454(4) (3), Z = 4 for 1, and a = 16.758(5) , b = 7.272(2) , c = 15.080(4) , beta = 106.334(5)A degrees, V = 1763.6(9) (3), Z = 4 for 2.

引用

页码：12 / 16

页数：5

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