Progress of electrode/electrolyte interfacial investigation of Li-ion batteries via in situ scanning probe microscopy

被引：50

作者：

Liu, Xingrui ^{[1
,2
]}

Wang, Dong ^{[1
]}

Wan, Lijun ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Key Lab Mol Nanostruct & Nanotechnol, Natl Lab Mol Sci, Beijing 100190, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

SCIENCE BULLETIN | 2015年 / 60卷 / 09期

基金：

中国国家自然科学基金;

关键词：

In situ scanning probe microscopy; Electrode/electrolyte interface; Solid electrolyte interphase; Li-ion battery; ATOMIC-FORCE MICROSCOPY; SOLID-ELECTROLYTE INTERPHASE; ELECTROCHEMICAL AFM; SILICON ELECTRODES; LITHIUM BATTERIES; LAYER DEPOSITION; SURFACE-REACTION; ELASTIC-MODULUS; ENERGY-STORAGE; YOUNGS MODULUS;

D O I：

10.1007/s11434-015-0763-6

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

The electrode/electrolyte interface plays a critical role in the performance of a Li-ion battery. In view of the dynamic and complex nature of the interface, in situ research approaches can provide valuable information of interfacial phenomena during battery operation. In situ scanning probe microscopy (SPM) is a powerful technique used for the interfacial investigation of the Li-ion batteries. The versatile SPM techniques and their various operation modes have been utilized to measure the morphology and other properties of the electrode interface at high resolution. Herein, we discuss the related SPM techniques to study the topography, mechanics and electrochemistry research of electrodes. Recent progresses of in situ SPM research on the electrode/electrolyte interface are summarized. Finally, the outlook of the technique is discussed.

引用

页码：839 / 849

页数：11

共 91 条

[1] Single-step direct measurement of amyloid fibrils stiffness by peak force quantitative nanomechanical atomic force microscopy [J].

Adamcik, Jozef ;

Berquand, Alexandre ;

Mezzenga, Raffaele .

APPLIED PHYSICS LETTERS, 2011, 98 (19)

[2] The formation and stability of the solid electrolyte interface on the graphite anode [J].

Agubra, Victor A. ;

Fergus, Jeffrey W. .

JOURNAL OF POWER SOURCES, 2014, 268 :153-162

[3] Review of selected electrode-solution interactions which determine the performance of Li and Li ion batteries [J].

Aurbach, D .

JOURNAL OF POWER SOURCES, 2000, 89 (02) :206-218

[4] The application of atomic force microscopy for the study of Li deposition processes [J].

Aurbach, D ;

Cohen, Y .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (11) :3525-3532

[5] In situ AFM imaging of surface phenomena on composite graphite electrodes during lithium insertion [J].

Aurbach, D ;

Koltypin, M ;

Teller, H .

LANGMUIR, 2002, 18 (23) :9000-9009

[6] Raman Microspectrometry Applied to the Study of Electrode Materials for Lithium Batteries [J].

Baddour-Hadjean, Rita ;

Pereira-Ramos, Jean-Pierre .

CHEMICAL REVIEWS, 2010, 110 (03) :1278-1319

[7] Reaction of Li with alloy thin films studied by in situ AFM [J].

Beaulieu, LY ;

Hatchard, TD ;

Bonakdarpour, A ;

Fleischauer, MD ;

Dahn, JR .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (11) :A1457-A1464

[8] The electrochemical reaction of lithium with tin studied by in situ AFM [J].

Beaulieu, LY ;

Beattie, SD ;

Hatchard, TD ;

Dahn, JR .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (04) :A419-A424

[9] A system for performing simultaneous in situ atomic force microscopy/optical microscopy measurements on electrode materials for lithium-ion batteries [J].

Beaulieu, LY ;

Cumyn, VK ;

Eberman, KW ;

Krause, LJ ;

Dahn, JR .

REVIEW OF SCIENTIFIC INSTRUMENTS, 2001, 72 (08) :3313-3319

[10] In Situ Atomic Force Microscopy of Lithiation and Delithiation of Silicon Nanostructures for Lithium Ion Batteries [J].

Becker, Collin R. ;

Strawhecker, Kenneth E. ;

McAllister, Quinn P. ;

Lundgren, Cynthia A. .

ACS NANO, 2013, 7 (10) :9173-9182

← 1 2 3 4 5 6 7 8 9 10 →