Synthesis of New Types of N,N-Disubstituted Aminomethylspirophosphoranes

被引：2
|
作者：
Prishchenko, Andrey A. [1 ]
Livantsov, Mikhail V. [1 ]
Novikova, Olga P. [1 ]
Livantsova, Ludmila I. [1 ]
Petrosyan, Valery S. [1 ]
机构：
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia
来源：
HETEROATOM CHEMISTRY | 2010年 / 21卷 / 07期
基金：
俄罗斯基础研究基金会;
关键词：
P-H BOND; SPIROPHOSPHORANES; DERIVATIVES; MECHANISM; REARRANGEMENT; ALCOHOLS; ENAMINES;
D O I：
10.1002/hc.20642
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Aminomethylation of several hydrospirophosphoranes and their derivatives, using chloro-, alkoxy-, and amino-substituted methylamines of various structures, is proposed as the convenient method for the synthesis of new N,N-disubstituted aminomethylspirophosphoranes. The unique reaction of aminomethylphosphonites with ethylene glycol also resulted in the aminomethylspirophosphoranes via the transesterification followed by the redox process. (C) 2010 Wiley Periodicals, Inc. Heteroatom Chem 21:515-520, 2010; View this article online at wileyonlinelibrary.com. DOI 10.1002/hc.20642
引用
收藏
页码：515 / 520
页数：6
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