Tracking silica in Earth's upper mantle using new sound velocity data for coesite to 5.8 GPa and 1073 K

The compressional and shear wave velocities for coesite have been measured simultaneously up to 5.8 GPa and 1073 K by ultrasonic interferometry for the first time. The shear wave velocity decreases with pressure along all isotherms. The resulting contrasts between coesite and stishovite reach similar to 34% and similar to 45% for P and S wave velocities, respectively, and similar to 64% and similar to 75% for their impedance at mantle conditions. The large velocity and impedance contrasts across coesite-stishovite transition imply that to generate the velocity and impedance contrasts observed at the X-discontinuity, only a small amount of silica would be required. The velocity jump dependences on silica, d(lnV(P))/d(SiO2) = 0.38 (wt %)(-1) and d(lnV(S))/d(SiO2) = 0.52 (wt %)(-1), are utilized to place constraints on the amount of silica in the upper mantle and provide a geophysical approach to track mantle eclogite materials and ancient subducted oceanic slabs.