Examining the role of Rh/Si cooperation in alkene hydrogenation by a pincer-type [P2Si]Rh complex

被引：26

作者：

Whited, Matthew T. ^{[1
]}

Deetz, Alexander M. ^{[1
]}

Donnell, Theodore M. ^{[1
]}

Janzen, Daron E. ^{[2
]}

机构：

[1] Carleton Coll, Dept Chem, Northfield, MN 55057 USA

[2] St Catherine Univ, Dept Chem & Biochem, St Paul, MN 55105 USA

来源：

DALTON TRANSACTIONS | 2016年 / 45卷 / 24期

基金：

美国国家科学基金会;

关键词：

REDUCTIVE ELIMINATION; SILYLENE COMPLEXES; BOND ACTIVATION; CARBON-MONOXIDE; LIGAND; REACTIVITY; RHODIUM; NICKEL; SI-C(SP(2)); CLEAVAGE;

D O I：

10.1039/c6dt00027d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A bis(phosphine)/triflatosilyl pincer-type Rh(I) complex can reversibly store one equivalent of H-2 across the Si-Rh bond upon triflate migration from silicon to rhodium. The triflatosilyl complex serves as an effective precatalyst for norbornene hydrogenation, but Si-OTf bond cleavage is not implicated in the major catalytic pathway. The combined findings suggest possible strategies for M/Si cooperation in catalytic processes.

引用

页码：9758 / 9761

页数：4

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