Improvement of lactic acid production from cellulose with the addition of Zn/Ni/C under alkaline hydrothermal conditions

被引:66
作者
Zhang, Shiping [1 ]
Jin, Fangming [1 ]
Hu, Jiajun [1 ]
Huo, Zhibao [1 ]
机构
[1] Tongji Univ, State Key Lab Pollut Control & Resources Reuse, Coll Environm Sci & Engn, Shanghai 200092, Peoples R China
基金
国家高技术研究发展计划(863计划); 中国国家自然科学基金;
关键词
Cellulose; Lactic acid; Hydrothermal condition; Response surface method (RSM); HOT-COMPRESSED WATER; HYDROGEN-PRODUCTION; CONVERSION; BIOMASS; GASIFICATION; HYDROLYSIS; CATALYSTS;
D O I
10.1016/j.biortech.2010.09.049
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
The effect of Zn, Ni and activated carbon on the yield of lactic acid from cellulose was investigated to improve the lactic acid yield under alkaline hydrothermal conditions. The results showed that the lactic acid yield increased greatly in the presence of Zn, Ni and activated carbon. Central composite response surface method (RSM) design experimentation was used to find the optimal concentrations of Zn, Ni, activated carbon and NaOH, which indicated that 0.02 g Zn, 0.03 g Ni, 0.07 g activated carbon and 2.5 mol/L NaOH were the optimal concentrations. Under this condition, the highest lactic acid yield was 42%, which was much higher than previous results using only NaOH (15%). The confirmatory experiments on lactic acid yield proved that the proposed model of lactic acid yield can accurately predict the lactic acid yield from cellulose. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1998 / 2003
页数:6
相关论文
共 28 条
[1]  
Amass W, 1998, POLYM INT, V47, P89, DOI 10.1002/(SICI)1097-0126(1998100)47:2<89::AID-PI86>3.0.CO
[2]  
2-F
[3]   Biomass gasification in supercritical water [J].
Antal, MJ ;
Allen, SG ;
Schulman, D ;
Xu, XD ;
Divilio, RJ .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2000, 39 (11) :4040-4053
[4]  
BRICKER M, 2005, J MOL CATAL-A CHEM, V239, P151
[5]   Liquefaction and gasification of cellulose with Na2CO3 and Ni in subcritical water at 350 °C [J].
Fang, Z ;
Minowa, T ;
Smith, RL ;
Ogi, T ;
Kozinski, JA .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2004, 43 (10) :2454-2463
[6]   Reaction chemistry and phase behavior of lignin in high-temperature and supercritical water [J].
Fang, Zhen ;
Sato, Takafumi ;
Smith, Richard L., Jr. ;
Inomata, Hiroshi ;
Arai, Kunio ;
Kozinski, Janusz A. .
BIORESOURCE TECHNOLOGY, 2008, 99 (09) :3424-3430
[7]   Catalytic hydrothermal deoxygenation of palmitic acid [J].
Fu, Jie ;
Lu, Xiuyang ;
Savage, Phillip E. .
ENERGY & ENVIRONMENTAL SCIENCE, 2010, 3 (03) :311-317
[8]   Hydrothermal conversion of municipal organic waste into resources [J].
Goto, M ;
Obuchi, R ;
Hiroshi, T ;
Sakaki, T ;
Shibata, M .
BIORESOURCE TECHNOLOGY, 2004, 93 (03) :279-284
[9]   The production of zinc by thermal dissociation of zinc oxide - Solar chemical reactor design [J].
Haueter, P ;
Moeller, S ;
Palumbo, R ;
Steinfeld, A .
SOLAR ENERGY, 1999, 67 (1-3) :161-167
[10]   Optimization of electron donors to improve CO2 fixation efficiency by a non-photosynthetic microbial community under aerobic condition using statistical experimental design [J].
Hu, Jia-jun ;
Wang, Lei ;
Zhang, Shi-ping ;
Fu, Xiao-hua ;
Le, Yi-quan .
BIORESOURCE TECHNOLOGY, 2010, 101 (18) :7062-7067