Synthesis, crystal and molecular structure and magnetic properties of an extended two-dimensional fumarato-bridged polymeric cobalt(II) complex [Co(μ-fumarato)(γ-methylpyridine)2(H2O)2]∞

被引：9

作者：

Zhang, KL ^{[1
]}

Xu, Y

You, XZ

机构：

[1] Yangzhou Univ, Chem & Chem Engn Coll, Yangzhou 225002, Peoples R China

[2] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

TRANSITION METAL CHEMISTRY | 2005年 / 30卷 / 03期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1007/s11243-004-6971-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An extended hydrogen-bonded two-dimensional fumarato-bridged complex [Co(mu-fumarato)(gamma-methylpyridine)(2)(H2O)(2)](infinity) has been synthesized and its crystal structure determined by single crystal X-ray analysis. The X-ray analysis reveals that the cobalt atom is positioned in distorted octahedral surroundings. An extended twodimensional structure was formed through interchain hydrogen bonding. Magnetic measurements showed the presence of weak antiferromagnetic exchange interactions between the cobalt(II) ions within the chain, based on the spin Hamilitonian H = -2J Sigma SiSi+ 1 (J = - 0.22 cm(-1)).

引用

页码：376 / 379

页数：4

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