High rate growth and luminescence properties of high-quality homoepitaxial diamond (100) films

被引:39
作者
Teraji, T [1 ]
Mitani, S [1 ]
Ito, T [1 ]
机构
[1] Osaka Univ, Grad Sch Engn, Dept Elect Engn, Suita, Osaka 5650871, Japan
来源
PHYSICA STATUS SOLIDI A-APPLIED RESEARCH | 2003年 / 198卷 / 02期
关键词
D O I
10.1002/pssa.200306615
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We have succeeded to grow chemical-vapor-deposited diamond films at reasonably high growth rates using high microwave power of 3.8 kW and high methane concentration ratios (CH4/H-2) of greater than or equal to4.0%. Growth rates of greater than or equal to2 mum/h have been attained for (100) homoepitaxial growth by utilizing high-density microwave plasma. These homoepitaxial films thus grown had flat surfaces with a small number of hillocks but no non-epitaxial crystallites over the whole area of 3 x 3 mm(2) high-pressure/high-temperature-synthesized Ib diamond substrates. These films yielded strong free-exciton-related emissions in their cathodolunimescence (CL) spectra taken at room temperature, indicating substantially high crystalline quality. Thus, the process technique using high-power microwave plasma for high-quality diamond growth is a remarkable advance in comparison with a very low rate growth of <0.1 mum/h using low microwave power system. Visible CL emissions originating from the Ib diamond substrate used was strongly observed from the overgrown thin homoepitaxial films with high quality. Both dependences of the CL intensities and CL images on the ovelayer thickness suggest large diffusion lengths (of several mum) for free carriers in the films, reflecting their high crystalline quality. The possible origin of the high-quality diamond growth process attained is discussed in relation to the high-power microwave plasma employed.
引用
收藏
页码:395 / 406
页数:12
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