Hydrothermal Syntheses and Structures of Lanthanide Coordination Polymers with 5-Aminoisophthalate and 1,10-Phenthroline

被引：1

作者：

Liu, Chong-Bo ^{[1
]}

Tang, Xing-Hua ^{[1
]}

Ding, Yuan ^{[1
]}

Shu, Hong-Ying ^{[1
]}

Huang, Zhi-Min ^{[1
]}

机构：

[1] Nanchang Hangkong Univ, Coll Environm & Chem Engn, Nanchang 330063, Peoples R China

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2011年 / 41卷 / 02期

基金：

中国国家自然科学基金;

关键词：

Crystal structure; 5-Aminoisophthalic acid; Lanthanide coordination polymers; Hydrothermal synthesis; Photoluminescence; SUPRAMOLECULAR ARCHITECTURE; COMPLEXES; CHANNELS; NETWORK; CHAIN; ACID; PHEN=1,10-PHENANTHROLINE; 1,10-PHENANTHROLINE; FRAMEWORKS;

D O I：

10.1007/s10870-010-9863-y

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Two new lanthanide coordination polymers, [Ln(2)(APA)(2)(HAPA)(2)(phen)(2)](n) [Ln = Pr (1), Eu (2); H(2)APA = 5-aminoisophthalic acid, phen = 1,10-Phenanthroline] have been synthesized by hydrothermal method, and characterized by single crystal X-ray diffraction, elemental analysis and IR spectra. Crystallographic data show that complexes 1 and 2 both crystallize in a triclinic system, space group P (1) over bar. The titled compounds own 2-D herringbone structures which are further constructed to form 3-D supramolecular structures by N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bondings. The thermogravimetric analyses were carried out to examine the thermal stability of the title complexes. And the photoluminescence property of 2 was investigated.

引用

页码：198 / 203

页数：6