Synthesis and Characterization of Iron(III) Complex Derived from Benzilmonoxime

被引：0

作者：

Soleimani, Esmaiel ^{[1
]}

Mitu, Liviu ^{[2
]}

机构：

[1] Shahrood Univ Technol, Fac Chem, Inorgan Res Lab, Shahrood, Iran

[2] Univ Pitesti, Dept Chem & Phys, Pitesti 110040, Romania

来源：

ASIAN JOURNAL OF CHEMISTRY | 2011年 / 23卷 / 04期

关键词：

Iron(III) complex; Electronic and infrared spectra; Benzilmonoxime; Facial isomer; X-ray diffraction; SPECTROPHOTOMETRIC METHOD; ALPHA-BENZILMONOXIME; COBALT; IRON;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction between benzilmonoxime and iron(III)acetylacetonate in presence of potassium acetate in methanol yielded an orange I precipitate. The electronic spectral data for this compound in DMF is in agreement with the octahedral coordination of iron(III). The IR data show that, bidentate ligand benzilmonoximate is bound to iron(III) through the oxygen atom of the carbonyl group and the nitrogen atom of the oxime group. The structure of the complex was determined by X-ray diffraction, cofirmed with an octahedral facial configuration.

引用

页码：1557 / 1560

页数：4

共 23 条

[1]

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[2] Intermolecular proton transfer in solid phase: A rare example of crystal-to-crystal transformation from hydroxo- to oxo-bridged iron(III) molecule-based magnet [J].