Modeling and optimization of voltage and treatment time for electrocoagulation removal of hexavalent chromium

被引:69
作者
Bhatti, Manpreet S. [1 ]
Reddy, Akepati S. [2 ]
Kalia, Rajeev K. [3 ]
Thukral, Ashwani K. [1 ]
机构
[1] Guru Nanak Dev Univ, Dept Bot & Environm Sci, Amritsar 143005, Punjab, India
[2] Thapar Univ, Dept Biotechnol & Environm Sci, Patiala 147001, Punjab, India
[3] GGSS Thermal Power Plant, Control & Instrumentat Maintenance Circle, Rupnagar, Punjab, India
关键词
Cr(VI) removal; Statistical modeling; Response surface methodology; Artificial neural network; Desirability plot; Design-Expert software; RESPONSE-SURFACE METHODOLOGY; SYNTHETIC WASTE-WATER; ELECTROCHEMICAL TREATMENT; AQUEOUS-SOLUTION; BORON REMOVAL; CR(VI); DYE; ELECTRODES; ALUMINUM; WASTEWATERS;
D O I
10.1016/j.desal.2010.10.055
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The present study was undertaken to optimize process variables, electrolysis voltage and treatment time for the electrocoagulation removal of hexavalent chromium (Cr(VI)). Response surface methodology (RSM) with center composite design was used to achieve energy efficient removal of Cr(VI). Predictive models using ANOVA and multiple response optimization revealed that optimal Cr(VI) removal efficiency occurred at 11 V and 18.6 min treatment time to give 50% Cr(VI) removal efficiency with a consumption of 15.46 KWh m(-3) energy. Multiple response optimization through a desirability function saves 32.3% energy consumption. The models explained 97.5% variability for Cr(VI) reduction efficiency and 99% variability for energy consumption. Artificial neural network (ANN) model was generated to validate the RSM predictions. Validation experiments were performed at proposed optimal conditions proved RSM and ANN predictions. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:157 / 162
页数:6
相关论文
共 36 条
[1]   Removal of Cr(VI) from polluted solutions by electrocoagulation: Modeling of experimental results using artificial neural network [J].
Aber, S. ;
Amani-Ghadim, A. R. ;
Mirzajani, V. .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 171 (1-3) :484-490
[2]   Optimization of C.I. Acid Red 14 azo dye removal by electrocoagulation batch process with response surface methodology [J].
Aleboyeh, A. ;
Daneshvar, N. ;
Kasiri, M. B. .
CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 2008, 47 (05) :827-832
[3]  
[Anonymous], 2004, DESIGN ANAL EXPT
[4]  
[Anonymous], DESIGN EXPERT SOFTWA
[5]  
*AWWA, 1998, STAND METH EX WAT WA
[6]   Electrocoagulation removal of Cr(VI) from simulated wastewater using response surface methodology [J].
Bhatti, Manpreet S. ;
Reddy, Akepati S. ;
Thukral, Ashwani K. .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 172 (2-3) :839-846
[7]   AN ANALYSIS OF TRANSFORMATIONS [J].
BOX, GEP ;
COX, DR .
JOURNAL OF THE ROYAL STATISTICAL SOCIETY SERIES B-STATISTICAL METHODOLOGY, 1964, 26 (02) :211-252
[8]   Electrochemical technologies in wastewater treatment [J].
Chen, GH .
SEPARATION AND PURIFICATION TECHNOLOGY, 2004, 38 (01) :11-41
[9]   The use of artificial neural networks (ANN) for modeling of decolorization of textile dye solution containing C. I. Basic Yellow 28 by electrocoagulation process [J].
Daneshvar, N. ;
Khataee, A. R. ;
Djafarzadeh, N. .
JOURNAL OF HAZARDOUS MATERIALS, 2006, 137 (03) :1788-1795
[10]  
Draper NR, 2004, APPL REGRESSION ANAL