Selective Catalytic Synthesis Using the Combination of Carbon Dioxide and Hydrogen: Catalytic Chess at the Interface of Energy and Chemistry

被引:723
作者
Klankermayer, Juergen [1 ]
Wesselbaum, Sebastian [1 ]
Beydoun, Kassem [1 ]
Leitner, Walter [1 ,2 ]
机构
[1] Rhein Westfal TH Aachen, Inst Tech & Makromol Chem, Worringerweg 2, D-52074 Aachen, Germany
[2] Max Planck Inst Kohlenforsch, Mulheim, Germany
关键词
catalysis; CO2; hydrogenation; green chemistry; GAS-SHIFT REACTION; IMMOBILIZED RUTHENIUM CATALYST; TRANSITION-METAL-COMPLEXES; FORMIC-ACID DECOMPOSITION; WATER-SOLUBLE RUTHENIUM; DEFINED IRON CATALYST; HYBRID GEL CATALYSTS; C-H BONDS; HOMOGENEOUS HYDROGENATION; METHANOL SYNTHESIS;
D O I
10.1002/anie.201507458
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The present Review highlights the challenges and opportunities when using the combination CO2/H-2 as a C-1 synthon in catalytic reactions and processes. The transformations are classified according to the reduction level and the bond-forming processes, covering the value chain from high volume basic chemicals to complex molecules, including biologically active substances. Whereas some of these concepts can facilitate the transition of the energy system by harvesting renewable energy into chemical products, others provide options to reduce the environmental impact of chemical production already in today's petrochemical-based industry. Interdisciplinary fundamental research from chemists and chemical engineers can make important contributions to sustainable development at the interface of the energetic and chemical value chain. The present Review invites the reader to enjoy this exciting area of "catalytic chess" and maybe even to start playing some games in her or his laboratory.
引用
收藏
页码:7296 / 7343
页数:48
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