Organic carbon stabilization in the fractal pore structure of Andosols

被引:76
|
作者
Chevallier, Tiphaine [1 ]
Woignier, Thierry [2 ,3 ]
Toucet, Joele [1 ]
Blanchart, Eric [1 ]
机构
[1] IRD, UMR Eco&Sols, Montpellier, France
[2] IRD, UMR Eco&Sols, PRAM, CNRS, Le Lamentin, France
[3] Univ Montpellier, CNRS, Montpellier, France
关键词
Soil organic carbon; Mesopore structure; Allophane; dV/dR; Fractal pore structure; SOC bioavailability; MICROBIAL BIOMASS; NATURAL GELS; XE-129; NMR; SOIL; MATTER; NITROGEN; MINERALIZATION; SEQUESTRATION; ADSORPTION; AGGREGATE;
D O I
10.1016/j.geoderma.2010.07.010
中图分类号
S15 [土壤学];
学科分类号
0903 ; 090301 ;
摘要
Despite the outstanding potential of Andosols for soil organic carbon (SOC) sequestration, the importance of the different mechanisms involved in protecting SOC against mineralization is still unclear. Previous studies have described allophane particles as having a fractal structure. One hypothesis is that SOC is adsorbed or trapped in this fractal structure and could be less available to microbes and enzymes. This paper aims to determine the fractal structure of allophanic soils, especially in mesopores (2-50 nm), and to establish a correlation between the SOC bioavailability and the fractal features of the allophane aggregates. The present study confirms the fractal structure of allophane aggregates. The structural features of the pores, measured using N-2 adsorption-desorption curves and SAXS for the nano-scale range, showed correlation with SOC bioavailability. SOC bioavailability decreased with the extent of the fractal structure. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:182 / 188
页数:7
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