Synthesis of amino-1,4-anhydro-D-pentitols and amino-1,5-anhydro-D-hexitols with the arabino configuration from (R)-glycidol

被引：11

作者：

Aragonès, S ^{[1
]}

Bravo, F ^{[1
]}

Díaz, Y ^{[1
]}

Matheu, MI ^{[1
]}

Castillón, S ^{[1
]}

机构：

[1] Univ Rovira & Virgili, Fac Quim, Dept Quim Anal & Quim Organ, Tarragona 43005, Spain

来源：

TETRAHEDRON-ASYMMETRY | 2003年 / 14卷 / 13期

关键词：

D O I：

10.1016/S0957-4166(03)00325-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

2-Amino-1,4-anhydro-pentitol and 3-amino-1,5-anhydro-4-deoxy-hexitol with the arabino configuration were synthesised from (R)-glycidol using a metathesis reaction as the key step. The dihydrofuran or dihydropyran products obtained after the metathesis reaction were subjected to epoxidation, epoxide opening with azide anion and finally azide reduction. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：1847 / 1856

页数：10

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