Bicontinuous phase in diblock copolymer melts with added homopolymer

被引:25
作者
Xi, HW [1 ]
Milner, ST [1 ]
机构
[1] EXXON RES & ENGN CO,ANNANDALE,NJ 08801
关键词
D O I
10.1021/ma950619z
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
We compute in the strong-segregation regime the phase diagram of A-B diblock copolymer with added B homopolymer to see if the bicontinuous phase can be stabilized by adding homopolymers. Our work is motivated by the results of Ajdari and Leibler, who showed using a bending expansion that a single copolymer bilayer in excess homopolymer is unstable to Gaussian bends if the copolymers are sufficiently asymmetric. Our methods, which are not limited to a bending expansion, determine the region of homopolymer concentration and copolymer asymmetry for which a bicontinuous phase might be stable.
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页码:2404 / 2411
页数:8
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共 21 条
  • [11] STABLE AND UNSTABLE PHASES OF A DIBLOCK COPOLYMER MELT
    MATSEN, MW
    SCHICK, M
    [J]. PHYSICAL REVIEW LETTERS, 1994, 72 (16) : 2660 - 2663
  • [12] A PARABOLIC DENSITY PROFILE FOR GRAFTED POLYMERS
    MILNER, ST
    WITTEN, TA
    CATES, ME
    [J]. EUROPHYSICS LETTERS, 1988, 5 (05): : 413 - 418
  • [13] THEORY OF THE GRAFTED POLYMER BRUSH
    MILNER, ST
    WITTEN, TA
    CATES, ME
    [J]. MACROMOLECULES, 1988, 21 (08) : 2610 - 2619
  • [14] Nitsche JJ, 1989, LECT MINIMAL SURFACE
  • [15] EQUILIBRIUM MORPHOLOGY OF BLOCK COPOLYMER MELTS
    OHTA, T
    KAWASAKI, K
    [J]. MACROMOLECULES, 1986, 19 (10) : 2621 - 2632
  • [16] STRONG-SEGREGATION THEORY OF BICONTINUOUS PHASES IN BLOCK-COPOLYMERS
    OLMSTED, PD
    MILNER, ST
    [J]. PHYSICAL REVIEW LETTERS, 1994, 72 (06) : 936 - 939
  • [17] STRONG-SEGREGATION THEORY OF BICONTINUOUS PHASES IN BLOCK-COPOLYMERS (VOL 72, PG 936, 1994)
    OLMSTED, PD
    MILNER, ST
    [J]. PHYSICAL REVIEW LETTERS, 1995, 74 (05) : 829 - 829
  • [18] SEMENOV AN, 1985, ZH EKSP TEOR FIZ, V61, P733
  • [19] ORDERED BICONTINUOUS DOUBLE-DIAMOND STRUCTURE OF STAR BLOCK COPOLYMERS - A NEW EQUILIBRIUM MICRODOMAIN MORPHOLOGY
    THOMAS, EL
    ALWARD, DB
    KINNING, DJ
    MARTIN, DC
    HANDLIN, DL
    FETTERS, LJ
    [J]. MACROMOLECULES, 1986, 19 (08) : 2197 - 2202
  • [20] CURVATURE INSTABILITY OF DIBLOCK COPOLYMER BILAYERS
    WANG, ZG
    [J]. MACROMOLECULES, 1992, 25 (14) : 3702 - 3705