Bicontinuous phase in diblock copolymer melts with added homopolymer

被引:25
|
作者
Xi, HW [1 ]
Milner, ST [1 ]
机构
[1] EXXON RES & ENGN CO,ANNANDALE,NJ 08801
关键词
D O I
10.1021/ma950619z
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
We compute in the strong-segregation regime the phase diagram of A-B diblock copolymer with added B homopolymer to see if the bicontinuous phase can be stabilized by adding homopolymers. Our work is motivated by the results of Ajdari and Leibler, who showed using a bending expansion that a single copolymer bilayer in excess homopolymer is unstable to Gaussian bends if the copolymers are sufficiently asymmetric. Our methods, which are not limited to a bending expansion, determine the region of homopolymer concentration and copolymer asymmetry for which a bicontinuous phase might be stable.
引用
收藏
页码:2404 / 2411
页数:8
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