Anti and gauche conformers of an inorganic butane analogue, NH3BH2NH2BH3

被引：22

作者：

Chen, Xuenian ^{[1
,2
]}

Gallucci, Judith ^{[1
]}

Campana, Charles ^{[3
]}

Huang, Zhenguo ^{[2
]}

Lingam, Hima Kumar ^{[1
]}

Shore, Sheldon G. ^{[1
]}

Zhao, Ji-Cheng ^{[2
]}

机构：

[1] Ohio State Univ, Dept Chem, Columbus, OH 43210 USA

[2] Ohio State Univ, Dept Mat Sci & Engn, Columbus, OH 43210 USA

[3] Bruker AXS Inc, Madison, WI 53711 USA

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 64期

关键词：

UNCONVENTIONAL HYDROGEN-BONDS; AMMONIA-BORANE; STAGGERED CONFORMATION; UNSYMMETRICAL CLEAVAGE; ASYMMETRIC CLEAVAGE; DIBORANE; HYPERCONJUGATION; OLIGOMERIZATION; CHEMISTRY; RELEASE;

D O I：

10.1039/c2cc33621a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structures of an inorganic butane analogue, NH3BH2NH2BH3 (DDAB), were determined using single crystal X-ray diffraction, revealing both anti and gauche conformations. The anti conformation is stabilized by intermolecular dihydrogen bonds in the crystal whereas two gauche conformations of DDAB observed in its 18-crown-6 adducts are stabilized by an intramolecular dihydrogen bond. The two gauche conformations show rotational isomerization but whether they are a pair of enantiomers is yet to be defined.

引用

页码：7943 / 7945

页数：3

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