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Prediction of a Strong Effect of a Weak Magnetic Field on Diffusion Assisted Reactions in Non Equilibrium Conditions
被引:6
|作者:
Kipriyanov, Alexey A.
[1
]
Purtov, Peter A.
[1
,2
]
机构:
[1] Inst Chem Kinet & Combust SB RAS, Novosibirsk, Russia
[2] Novosibirsk State Univ, Novosibirsk 630090, Russia
关键词:
Radicals;
Magnetic effects;
Nonlinear phenomena;
NUCLEAR-POLARIZATION;
ELECTROMAGNETIC-FIELDS;
SPIN;
BIRADICALS;
DYNAMICS;
PEROXIDASE;
PHOTOLYSIS;
MECHANISM;
D O I:
10.5012/bkcs.2012.33.3.1009
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
The influence of magnetic fields on chemical processes has long been the subject of interest to researchers. For this time numerous investigations show that commonly the effect of a magnetic field on chemical reactions is insignificant with impact less than 10 percent. However, there are some papers that point to the observation of external magnetic field effect on chemical and biochemical systems actually having a significant impact on the reactions. Thus, of great interest is an active search for rather simple but realistic models, that are based on physically explicit assumptions and able to account for a strong effect of low magnetic fields. The present work theoretically deals with two models explaining how an applied weak magnetic field might influence the steady state of a non-equilibrium chemical system. It is assumed that external magnetic field can have effect on the rates of radical reactions occurring in a system. This, in turn, leads to bifurcation of the nonequilibrium stationary state and, thus, to a drastic change in the properties of chemical systems (temperature and reagent concentration).
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页码:1009 / 1014
页数:6
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