Preparation of three-dimensionally ordered inorganic/organic bi-continuous composite proton conducting membranes

被引:14
作者
Chen, SL [1 ]
Xu, KQ
Dong, P
机构
[1] China Univ Petr Changping, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China
[2] China Univ Petr Changping, Dept Chem Engn, Beijing 102249, Peoples R China
关键词
D O I
10.1021/cm050709a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The synthesis of a three-dimensionally (3-D) ordered SiO 2/sulfonated poly(arylene ether sulfone) PSU composite membranes, was analyzed. Uniform PS particles were synthesized through the microemulsion method. PS particles, the PS/SiO2film, and the 3-D ordered composite membranes were examined by a HITACHI S-4200 scanning electron microscope. The transmission electron microscopy showed that the synthesized PS particles were uniform, with a mean diameter of 212∓6 nm. The results show that the ordered structure of the SiO2/PS materials was evidenced by the photonic band gap of the material.
引用
收藏
页码:5880 / 5883
页数:4
相关论文
共 28 条
[1]   Silicon oxide Nafion composite membranes for proton-exchange membrane fuel cell operation at 80-140° C [J].
Adjemian, KT ;
Lee, SJ ;
Srinivasan, S ;
Benziger, J ;
Bocarsly, AB .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (03) :A256-A261
[2]   Investigation of PEMFC operation above 100°C employing perfluorosulfonic acid silicon oxide composite membranes [J].
Adjemian, KT ;
Srinivasan, S ;
Benziger, J ;
Bocarsly, AB .
JOURNAL OF POWER SOURCES, 2002, 109 (02) :356-364
[3]   Influence of the acid-base characteristics of inorganic fillers on the high temperature performance of composite membranes in direct methanol fuel cells [J].
Aricò, AS ;
Baglio, V ;
Di Blasi, A ;
Creti, P ;
Antonucci, PL ;
Antonucci, V .
SOLID STATE IONICS, 2003, 161 (3-4) :251-265
[4]   Effect of equivalent weight on electrochemical mass transport properties of oxygen in proton exchange membranes based on sulfonated α,β,β-trifluorostyrene (BAM®) and sulfonated styrene-(ethylene-butylene)-styrene triblock (DAIS-analytical) copolymers [J].
Basura, VI ;
Chuy, C ;
Beattie, PD ;
Holdcroft, S .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2001, 501 (1-2) :77-88
[5]  
Bauer B, 2000, J NEW MAT ELECTR SYS, V3, P93
[6]   Proton conducting membranes based on PEG/SiO2 nanocomposites for direct methanol fuel cells [J].
Chang, HY ;
Lin, CW .
JOURNAL OF MEMBRANE SCIENCE, 2003, 218 (1-2) :295-306
[7]  
CHEN SL, 2005, IN PRESS J POWER SOU, V152
[8]   Transport properties of Nafion™ composite membranes for proton-exchange membranes fuel cells [J].
Damay, F ;
Klein, LC .
SOLID STATE IONICS, 2003, 162 :261-267
[9]   Sulfonated and crosslinked polyphosphazene-based proton-exchange membranes [J].
Guo, QH ;
Pintauro, PN ;
Tang, H ;
O'Connor, S .
JOURNAL OF MEMBRANE SCIENCE, 1999, 154 (02) :175-181
[10]   Thermal stability of styrene grafted and sulfonated proton conducting membranes based on poly(vinylidene fluoride) [J].
Hietala, S ;
Koel, M ;
Skou, E ;
Elomaa, M ;
Sundholm, F .
JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (05) :1127-1132