PρT Behavior of Several Chemicals from Biomass

被引:47
作者
Guerrero, Hernando [2 ]
Lafuente, Carlos [2 ]
Royo, Felix [2 ]
Lomba, Laura [1 ]
Giner, Beatriz [1 ]
机构
[1] Univ San Jorge, Fac Ciencias Salud, Zaragoza 50830, Spain
[2] Univ Zaragoza, Fac Ciencias, Dept Quim Fis, E-50009 Zaragoza, Spain
关键词
WIDE TEMPERATURE; LEVULINIC ACID; PRESSURE RANGE; DENSITIES; EQUATION; TOLUENE;
D O I
10.1021/ef200653s
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Densities of levulinic acid, ethyl levulinate, butyl levulinate, furfural, and furfuryl alcohol have been measured using a high-pressure, high-temperature vibrating tube densimeter system over a temperature range from 283.15 to 338.15 K and a pressure range from 0.1 to 60.0 MPa. In the case of levulinic acid, the temperature range was from 308.15 to 338.15 K The experimental densities have been satisfactorily correlated with the temperature and pressure using the TRIDEN equation. Finally, from the measured densities, some thermodynamic properties, isobaric thermal expansion and isothermal compressibility, have been calculated.
引用
收藏
页码:3009 / 3013
页数:5
相关论文
共 20 条
[1]   Liquid densities at elevated pressures of n-alkanes from C-5 to C-16: A critical evaluation of experimental data [J].
Cibulka, I ;
Hnedkovsky, L .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1996, 41 (04) :657-668
[2]   On the properties of 1-butyl-3-methylimidazolium octylsulfate ionic liquid [J].
Davila, Maria J. ;
Aparicio, Santiago ;
Alcalde, Rafael ;
Garcia, Begona ;
Leal, Jose M. .
GREEN CHEMISTRY, 2007, 9 (03) :221-232
[3]  
DAVILA MJ, 2009, GREEN CHEM, V11, P65
[4]  
DEMIRIZ AM, 1987, THESIS RUHR U BOCHUM
[5]   THE TAIT EQUATION - 100 YEARS ON [J].
DYMOND, JH ;
MALHOTRA, R .
INTERNATIONAL JOURNAL OF THERMOPHYSICS, 1988, 9 (06) :941-951
[7]   HEAT CAPACITIES OF SEVERAL ORGANIC LIQUIDS [J].
HOUGH, EW ;
MASON, DM ;
SAGE, BH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1950, 72 (12) :5775-5777
[8]   Densities of sulfur hexafluoride and dinitrogen monoxide over a wide temperature and pressure range in the sub- and supercritical states [J].
Ihmels, EC ;
Gmehling, J .
INTERNATIONAL JOURNAL OF THERMOPHYSICS, 2002, 23 (03) :709-743
[9]   Densities of toluene, carbon dioxide, carbonyl sulfide, and hydrogen sulfide over a wide temperature and pressure range in the sub- and supercritical state [J].
Ihmels, EC ;
Gmehling, J .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2001, 40 (20) :4470-4477
[10]   The temperature dependency of the molecular free surface energy of fluids in temperature area from-80 to+1650(o) C [J].
Jaeger, FM .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1917, 101 (1/3) :1-214