An all-inorganic, stable, and highly active tetraruthenium homogeneous catalyst for water oxidation

被引：519

作者：

Geletii, Yurii V. ^{[2
]}

Botar, Bogdan ^{[1
]}

Koegerler, Paul ^{[1
]}

Hillesheim, Daniel A. ^{[2
]}

Musaev, Djamaladdin G. ^{[3
]}

Hill, Craig L. ^{[2
]}

机构：

[1] Forschungszentrum Julich, Inst Festkorperforsch, D-52425 Julich, Germany

[2] Emory Univ, Dept Chem, Atlanta, GA 30322 USA

[3] Emory Univ, Cherry L Emerson Ctr Sci Computat, Atlanta, GA 30322 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 21期

关键词：

dioxygen generation; electrochemistry; homogeneous catalysis; oxidation; polyoxometalates;

D O I：

10.1002/anie.200705652

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Oxidation without organics: A tetraruthenium polyoxometalate (see picture; Ru blue, O red, Si yellow, W black) catalyzes the rapid oxidation of H2O to O2 in water at ambient temperature, and shows considerable stability under turnover conditions. The complex was characterized by several methods, including X-ray crystallography and cyclic voltammetry. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3896 / 3899

页数：4

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