Synthesis of highly functionalized fluorinated porphyrins

被引:12
作者
Briza, Tomas [1 ,2 ]
Kaplanek, Robert [1 ,2 ]
Havlik, Martin [1 ]
Dolensky, Bohumil [1 ]
Kejik, Zdenek [1 ]
Martasek, Pavel [2 ]
Kral, Vladimir [1 ]
机构
[1] Inst Chem Technol Prague, Dept Analyt Chem, Prague 16628 6, Czech Republic
[2] Charles Univ Prague, Fac Med 1, Prague 12108 2, Czech Republic
关键词
fluorinated dendritic structure; polyfluoroalkylated porphyrin; fluorous; porphyrin core;
D O I
10.1080/10610270601120371
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Highly functionalized fluorinated porphyrins were synthesized by a convergent strategy. Nucleophilic substitution using fluorinated branched unit and 5,10,15,20-tetrakis(pentafluorophenyl)porphyrin afforded highly functionalized fluorinated porphyrin 8 containing 24 fluorinated chains in the peripheral region.
引用
收藏
页码:237 / 242
页数:6
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